Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions

被引：0

作者：

Hajipour, R ^{[1
]}

Mohammadpoor-Baltork, I

Kianfar, G

机构：

[1] Isfahan Univ Technol, Coll Chem, Esfahan, Iran

[2] Isfahan Univ, Dept Chem, Esfahan, Iran

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1999年 / 38卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)persulfate (BAABCPS) 1 readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium persulfate, converts oximes and alpha-sulfinyl oximes to the corresponding carbonyl compounds and beta-keto sulfoxides respectively, the yields and enantiomeric purity are excellent.

引用

页码：221 / 224

页数：4

共 38 条

[21] Oxidation of alcohols with 1-decyl-4-aza-1-azonia-bicyclo[2.2.2]-octane chlorochromate under conventional and solvent-free conditions
A. R. Hajipour
H. R. Bagheri
A. E. Ruoho
Russian Journal of Organic Chemistry, 2006, 42 : 844 - 848
[22] 1,4-Diazabicyclo[2.2.2]octane 1,4-bis(oxide)-bis(hydrogen peroxide)/MClx as a novel heterogeneous system for the oxidation of urazoles under mild conditions
Zolfigol, M.A., 1673, Chemical Society of Japan (76):
[23] 1,4-diazabicyclo[2.2.2]octane 1,4-bis(oxide)-bis(hydrogen peroxide)/MClx as a novel heterogeneous system for the oxidation of urazoles under mild conditions
Zolfigol, MA
Salehi, P
Mallakpour, SE
Torabi, M
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (08) : 1673 - 1674
[24] An environmentally benign synthesis of 1-benzyl-4-aza-1-azonia-bicyclo[2.2.2]octane tribromide and its application as an efficient and selective reagent for oxidation of sulfides to sulfoxides in solution and solvent-free conditions
Pourmousavi, S. A.
Salehi, P.
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2008, 29 (07) : 1332 - 1334
[25] A potential molecular ferroelectric material: poly[[bis(1-aza-4-azoniabicyclo[2.2.2]octane)di-μ3-chlorido-tetra-μ2-chlorido-dichloridotricadmium(II)] dihydrate]
Zhou, Qin-Qin
Jin, Lei
Liao, Wei-Qiang
Zhang, Yi
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2013, 69 : 237 - U91
[26] Bis(1-benzyl-3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7] decane) peroxodisulfate:: A mild and efficient oxidation of organic compounds under anhydrous and aprotic conditions
Wu, MH
Yang, GC
Chen, ZX
SYNTHETIC COMMUNICATIONS, 2000, 30 (17) : 3127 - 3131
[27] 1-FLUORO-4-HYDROXY-1,4-DIAZONIABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE) AS A NEW, EFFECTIVE REAGENT FOR SELECTIVE FLUOROFUNCTIONALISATION OF ALKENES UNDER MILD REACTION CONDITIONS
STAVBER, S
ZUPAN, M
POSS, AJ
SHIA, GA
TETRAHEDRON LETTERS, 1995, 36 (37) : 6769 - 6772
[28] Silica bonded n-propyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride (SB-DABCO): A highly efficient, reusable and new heterogeneous catalyst for the synthesis of 4H-benzo[b]pyran derivatives
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APPLIED CATALYSIS A-GENERAL, 2011, 402 (1-2) : 11 - 22
[29] 1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]-octane chlorochromate (DBDABOCC): A mild and selective reagent for efficient oxidation of organic compounds under non-aqueous conditions
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INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2000, 39 (11): : 863 - 866
[30] Magnetic hydroxyapatite-immobilized 1,4-diazabicyclo [2.2.2] octane as a highly efficient and eco-friendly nanocatalyst for the promotion of nucleophilic substitution reactions of benzyl halides under green conditions
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Ebrahim Mehdipour
Reaction Kinetics, Mechanisms and Catalysis, 2017, 122 : 1159 - 1174

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