Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions

被引：0

作者：

Hajipour, R ^{[1
]}

Mohammadpoor-Baltork, I

Kianfar, G

机构：

[1] Isfahan Univ Technol, Coll Chem, Esfahan, Iran

[2] Isfahan Univ, Dept Chem, Esfahan, Iran

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1999年 / 38卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)persulfate (BAABCPS) 1 readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium persulfate, converts oximes and alpha-sulfinyl oximes to the corresponding carbonyl compounds and beta-keto sulfoxides respectively, the yields and enantiomeric purity are excellent.

引用

页码：221 / 224

页数：4

共 38 条

[1] 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane periodate: a mild and efficient oxidant for the cleavage of oxime double bonds under anhydrous conditions
Hajipour, AR
Mahboubghah, N
JOURNAL OF CHEMICAL RESEARCH, 1998, (03) : 122 - 123
[2] Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate: A mild and efficient oxidant for cleavage of nitrogen double bonds and oxidation of alcohols under anhydrous conditions
Hajipour, AR
Mohammadpoor-Baltork, I
Kianfar, G
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (11) : 2655 - 2659
[3] 1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide as a regenerable and useful reagent for bromination of phenols under mild conditions
Hajipour, AR
Pourmousavi, SA
Ruoho, AE
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2006, 45 (03): : 796 - 800
[4] Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate: A mild and efficient oxidant for oxidation of thiols, sulfides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds
Hajipour, AR
Mohammadpoor-Baltork, I
Kianfar, G
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1999, 38 (05): : 607 - 610
[5] 1-Benzyl-1-aza-4-azoniabicyclo[2.2.2]-octane periodate as new oxidant for oxidation of thiols and sulfides to the corresponding disulfides and sulfoxides under anhydrous conditions
Hajipour, AR
Mahboubghah, N
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1998, 37 (10): : 1041 - 1043
[6] 1-benzyl-4-aza-1-azoniabicyclo[2.2.2] octane tribromide as a highly reactive brominating agent for aniline derivatives
Hajipour, AR
Imanieh, H
Pourmousavi, SA
SYNTHETIC COMMUNICATIONS, 2004, 34 (24) : 4597 - 4604
[7] Preparation of 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide and its application as a mild and chemoselective catalyst for thioacetalization of carbonyl compounds
Pourmousavi, Seied Ali
Hadavandkhani, Majid
JOURNAL OF SULFUR CHEMISTRY, 2009, 30 (01) : 37 - 45
[8] Solid state deprotection of thioacetals and thioketals using 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane periodate and aluminum chloride
Hajipour, AR
Ruoho, AE
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2005, 37 (03) : 298 - 303
[9] Hiyama cross-coupling reaction catalyzed by a palladium salt of 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride under microwave irradiation
Hajipour, Abdol R.
Rafiee, Fatemeh
Najafi, Narges
APPLIED ORGANOMETALLIC CHEMISTRY, 2014, 28 (04) : 217 - 220
[10] MODIFIED BOROHYDRIDE AGENTS, 1-BENZYL-4-AZA-1-AZONIABICYCLO[2.2.2]OCTANE TETRAHYDROBORATE (BAAOTB) VERSUS TETRABUTYLAMMONIUM TETRAHYDROBORATE (TBATB) - EFFICIENT, SELECTIVE, AND VERSATILE REDUCING AGENTS
FIROUZABADI, H
AFSHARIFAR, GR
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (09) : 2595 - 2602

← 1 2 3 4 →