Kinetics of ozone-olefin reactions in aqueous solutions

被引：1
|
作者：
Shafikov, NY [1 ]
Zimin, YS [1 ]
Gerchikov, AY [1 ]
Komissarov, VD [1 ]
机构：
[1] Bashkortostan State Univ, Ufa 450074, Russia
来源：
KINETICS AND CATALYSIS | 2005年 / 46卷 / 06期
关键词：
D O I：
10.1007/s10975-005-0142-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of the reactions of ozone with 12 substituted olefins in aqueous solutions at 293 K are studied by the stopped-flow method. Second-order rate constants are determined for these reactions. The dependence of the reactivity of olefins in H2O on their structure can be described by the Taft equation.
引用
收藏
页码：826 / 829
页数：4
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