Kinetics of ozone-olefin reactions in aqueous solutions

被引：1
|
作者：
Shafikov, NY [1 ]
Zimin, YS [1 ]
Gerchikov, AY [1 ]
Komissarov, VD [1 ]
机构：
[1] Bashkortostan State Univ, Ufa 450074, Russia
来源：
KINETICS AND CATALYSIS | 2005年 / 46卷 / 06期
关键词：
D O I：
10.1007/s10975-005-0142-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of the reactions of ozone with 12 substituted olefins in aqueous solutions at 293 K are studied by the stopped-flow method. Second-order rate constants are determined for these reactions. The dependence of the reactivity of olefins in H2O on their structure can be described by the Taft equation.
引用
收藏
页码：826 / 829
页数：4
相关论文
共 50 条
  • [41] KINETICS OF LIGNIN OXIDATION BY OZONE IN AQUEOUS-SOLUTIONS
    BENKO, EM
    KOVALEVA, VV
    MITROFANOVA, AN
    VOBLIKOVA, VA
    PRYAKHIIN, AN
    LUNIN, VV
    ZHURNAL FIZICHESKOI KHIMII, 1994, 68 (09): : 1580 - 1583
  • [42] Kinetics and simulation of the decomposition of ozone in acidic aqueous solutions
    Hahn, J
    Lachmann, G
    Pienaar, JJ
    SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE, 2000, 53 (02): : 132 - 138
  • [43] Kinetics of decoloring aqueous azo dye solutions with ozone
    Kerzhner, B.K.
    Kozhanov, V.A.
    Sid'ko Ya., R.
    Shevchenko, M.A.
    1600, (08):
  • [44] Kinetics of oxidation of aliphatic alcohols by ozone in aqueous solutions
    Gerchikov, AY
    Zimin, YS
    Trukhanova, NV
    Evgrafov, VN
    REACTION KINETICS AND CATALYSIS LETTERS, 1999, 68 (02): : 257 - 263
  • [45] Kinetics of oxidation of aliphatic alcohols by ozone in aqueous solutions
    A. Ya. Gerchikov
    Yu. S. Zimin
    N. V. Trukhanova
    V. N. Evgrafov
    Reaction Kinetics and Catalysis Letters, 1999, 68 : 257 - 263
  • [46] ABSORPTION KINETICS OF OZONE IN AQUEOUS-SOLUTIONS OF MALATHION
    BENITEZ, FJ
    BELTRANHEREDIA, J
    GONZALEZ, T
    OZONE-SCIENCE & ENGINEERING, 1991, 13 (04) : 487 - 499
  • [47] Rate constants for the reactions of ozone with chlorophenols in aqueous solutions
    Benitez, FJ
    Beltrán-Heredia, J
    Acero, JL
    Rubio, FJ
    JOURNAL OF HAZARDOUS MATERIALS, 2000, 79 (03) : 271 - 285
  • [48] KINETICS OF ELECTROCHEMICAL REACTIONS IN AQUEOUS ORGANIC SOLUTIONS
    AFANASEV, BN
    MERKULOVA, GI
    SOVIET ELECTROCHEMISTRY, 1985, 21 (07): : 803 - 809
  • [49] Determination of fast ozone reactions in aqueous solution by competition kinetics
    Von Sonntag, C. (vonsonntag@mpi-muelheim.mpg.de), 2000, Royal Society of Chemistry
  • [50] Determination of fast ozone reactions in aqueous solution by competition kinetics
    Muñoz, F
    von Sonntag, C
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, 4 : 661 - 664
12345