Kinetics of Polyol Oxidation by Ozone in Aqueous Solutions

被引：0
|
作者：
Yu. S. Zimin
N. V. Trukhanova
I. V. Strel'tsova
V. D. Komissarov
机构：
[1] Bashkortostan State University,
[2] Ufa,undefined
来源：
Kinetics and Catalysis | 2000年 / 41卷
关键词：
Oxidation; Alcohol; Ethylene; Physical Chemistry; Aqueous Solution;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Spectrophotometry is applied to study the oxidation of ethylene glycol, triethylene glycol, glycerol, etriol, pentaerithritol and mannitol by ozone in aqueous solutions at 277–304 K. Rate constants and activation parameters of the reaction are measured. It is proposed that the oxidation of these alcohols by ozone occurs via the same mechanism. The formation of an intermediate complex is a rate-limiting step in the case of diols; the decomposition of the complex is a rate-limiting step for tri- to hexatomic alcohols.
引用
收藏
页码：749 / 752
页数：3
相关论文
共 50 条
  • [1] Kinetics of polyol oxidation by ozone in aqueous solutions
    Zimin, YS
    Trukhanova, NV
    Strel'tsova, IV
    Komissarov, VD
    KINETICS AND CATALYSIS, 2000, 41 (06) : 749 - 752
  • [2] KINETICS OF THE OXIDATION OF AMMONIA IN AQUEOUS SOLUTIONS BY OZONE
    PAPKO, SI
    ZHURNAL FIZICHESKOI KHIMII, 1957, 31 (07): : 1636 - 1639
  • [3] Kinetics of oxidation of dioxanes by ozone in aqueous solutions
    Yu.S. Zimin
    A.A. Gusmanov
    G.I. Hairetdinova
    R.M. Makaeva
    Reaction Kinetics and Catalysis Letters, 2002, 76 : 393 - 399
  • [4] Kinetics of oxidation of dioxanes by ozone in aqueous solutions
    Zimin, YS
    Gusmanov, AA
    Hairetdinova, GI
    Makaeva, RM
    REACTION KINETICS AND CATALYSIS LETTERS, 2002, 76 (02): : 393 - 399
  • [5] The kinetics of cyclohexanone oxidation by ozone in aqueous solutions
    Zimin, YS
    Trukhanova, NV
    Rafikova, GM
    Komissarov, VD
    KINETICS AND CATALYSIS, 1998, 39 (04) : 467 - 468
  • [6] KINETICS OF LIGNIN OXIDATION BY OZONE IN AQUEOUS-SOLUTIONS
    BENKO, EM
    KOVALEVA, VV
    MITROFANOVA, AN
    VOBLIKOVA, VA
    PRYAKHIIN, AN
    LUNIN, VV
    ZHURNAL FIZICHESKOI KHIMII, 1994, 68 (09): : 1580 - 1583
  • [7] Kinetics of oxidation of aliphatic alcohols by ozone in aqueous solutions
    Gerchikov, AY
    Zimin, YS
    Trukhanova, NV
    Evgrafov, VN
    REACTION KINETICS AND CATALYSIS LETTERS, 1999, 68 (02): : 257 - 263
  • [8] Kinetics of oxidation of aliphatic alcohols by ozone in aqueous solutions
    A. Ya. Gerchikov
    Yu. S. Zimin
    N. V. Trukhanova
    V. N. Evgrafov
    Reaction Kinetics and Catalysis Letters, 1999, 68 : 257 - 263
  • [9] Kinetics of oxidation of FE(II) ions by ozone in aqueous solutions
    Ben'ko, EM
    Bokova, MN
    Mitrofanova, AN
    Pryakhin, AN
    Lunin, VV
    ZHURNAL FIZICHESKOI KHIMII, 1998, 72 (08): : 1531 - 1533
  • [10] KINETICS AND MECHANISM OF THE OXIDATION OF SULFUR(IV) BY OZONE IN AQUEOUS-SOLUTIONS
    BOTHA, CF
    HAHN, J
    PIENAAR, JJ
    VANELDIK, R
    ATMOSPHERIC ENVIRONMENT, 1994, 28 (20) : 3207 - 3212
12345