Facile and chemo-selective synthesis of tertiary alkyl isothiocyanates from alcohols

被引：17
|
作者：
Miyake, Hideyoshi [1 ]
Nakao, Yuichi [1 ]
Sasaki, Mitsuru [1 ]
机构：
[1] Kobe Univ, Grad Sch Agr Sci, Kobe, Hyogo 6578501, Japan
来源：
TETRAHEDRON | 2007年 / 63卷 / 42期
关键词：
D O I：
10.1016/j.tet.2007.08.014
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
When tert-alcohols were treated with ( COOH) 2 and NaSCN in the presence of iodine, tertiary alkyl isothiocyanates were obtained in good yield, whereas the corresponding thiocyanates were obtained in low yield in the absence of iodine. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：10433 / 10436
页数：4
相关论文
共 50 条
  • [21] Facile synthesis of simple mono-alkyl phosphates from phosphoric acid and alcohols
    Dueymes, Cyril
    Pirat, Celine
    Pascal, Robert
    TETRAHEDRON LETTERS, 2008, 49 (36) : 5300 - 5301
  • [22] NOVEL SYNTHESIS OF ASYMMETRIC ALKYL PEROXIDES USING TERTIARY ALCOHOLS
    BOURGEOIS, MJ
    MONTAUDON, E
    MAILLARD, B
    TETRAHEDRON, 1993, 49 (12) : 2477 - 2484
  • [23] SYNTHESIS OF HETEROCYCLES FROM ARYL ISOTHIOCYANATES AND ALKYL AZIDES
    LABBE, G
    VERHELST, G
    TOPPET, S
    JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (07): : 1159 - 1163
  • [24] A facile process to optimize performance of regenerated Nd-Fe-B sintered magnets: Chemo-selective dissolution washing
    Xu, Haibo
    Lu, Qingmei
    Yu, Lichao
    Cong, Liying
    Tian, Haowen
    Liu, Weiqiang
    Liu, Youhao
    Wang, Yunqiao
    Chen, Jingwu
    Yi, Xiaofei
    Wu, Qiong
    Yue, Ming
    JOURNAL OF RARE EARTHS, 2023, 41 (12) : 1976 - 1983
  • [25] Area-selective atomic layer deposition of Ru thin films by chemo-selective inhibition of alkyl aldehyde molecules on nitride surfaces
    Lee, Jinseon
    Oh, Jieun
    Kim, Jiwon
    Oh, Hongjun
    Shong, Bonggeun
    Kim, Woo-Hee
    APPLIED SURFACE SCIENCE, 2024, 662
  • [26] Three-Component Chemo-Selective Synthesis of N-(o-Alkenylaryl) Pyrazoles by Pyrazole Annulation and Rh-Catalyzed Chemo-Selective Aryl C-H Addition Cascade
    Chen, Demao
    Zhou, Liyun
    Wen, Chengping
    Wan, Jie-Ping
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (13): : 8619 - 8627
  • [27] Enantio- & chemo-selective preparation of enantiomerically enriched aliphatic nitro alcohols using Candida parapsilosis ATCC 7330
    Venkataraman, Sowmyalakshmi
    Chadha, Anju
    RSC ADVANCES, 2015, 5 (90): : 73807 - 73813
  • [28] Experimental and theoretical insights for designing Zn2+ complexes to trigger chemo-selective hetero-coupling of alcohols
    Samanta, Arup
    Behera, Prativa
    Chaubey, Amit
    Mondal, Avijit
    Pal, Debjyoti
    Mohar, Kailash
    Roy, Lisa
    Srimani, Dipankar
    CHEMICAL COMMUNICATIONS, 2024, 60 (30) : 4056 - 4059
  • [29] Chemo-selective Suzuki-Miyaura reactions: Synthesis of highly substituted [1,6]-naphthyridines
    Yadavalli, Suneel Kumar
    Fazlur-Rahman, Nawaz Khan
    CHINESE CHEMICAL LETTERS, 2017, 28 (07) : 1607 - 1612
  • [30] A facile process to optimize performance of regenerated Nd-Fe-B sintered magnets:Chemo-selective dissolution washing
    Haibo Xu
    Qingmei Lu
    Lichao Yu
    Liying Cong
    Haowen Tian
    Weiqiang Liu
    Youhao Liu
    Yunqiao Wang
    Jingwu Chen
    Xiaofei Yi
    Qiong Wu
    Ming Yue
    Journal of Rare Earths, 2023, 41 (12) : 1976 - 1983
12345