Facile and chemo-selective synthesis of tertiary alkyl isothiocyanates from alcohols

被引：17

作者：

Miyake, Hideyoshi ^{[1
]}

Nakao, Yuichi ^{[1
]}

Sasaki, Mitsuru ^{[1
]}

机构：

[1] Kobe Univ, Grad Sch Agr Sci, Kobe, Hyogo 6578501, Japan

来源：

TETRAHEDRON | 2007年 / 63卷 / 42期

关键词：

D O I：

10.1016/j.tet.2007.08.014

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

When tert-alcohols were treated with ( COOH) 2 and NaSCN in the presence of iodine, tertiary alkyl isothiocyanates were obtained in good yield, whereas the corresponding thiocyanates were obtained in low yield in the absence of iodine. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：10433 / 10436

页数：4

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