NOVEL SYNTHESIS OF ASYMMETRIC ALKYL PEROXIDES USING TERTIARY ALCOHOLS

被引：20
|
作者：
BOURGEOIS, MJ [1 ]
MONTAUDON, E [1 ]
MAILLARD, B [1 ]
机构：
[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,URA 35,F-33405 TALENCE,FRANCE
来源：
TETRAHEDRON | 1993年 / 49卷 / 12期
关键词：
D O I：
10.1016/S0040-4020(01)86326-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of alkyl hydroperoxides (1ary, 2ary or 3ary) upon tertiary alkyl trichloroacetimidates under acidic catalysis yielded unsymetrical dialkyl peroxides with yields in the range 30-70%.
引用
收藏
页码：2477 / 2484
页数：8
相关论文
共 50 条
  • [1] Asymmetric Synthesis of Tertiary Benzylic Alcohols
    Antczak, Monika I.
    Cai, Feng
    Ready, Joseph M.
    ORGANIC LETTERS, 2011, 13 (02) : 184 - 187
  • [2] NOVEL SYNTHESIS OF TERTIARY ALKYL, SECONDARY AND TERTIARY BENZYL, AND ALLYL SELENIDES FROM THE CORRESPONDING ALCOHOLS
    CLAREMBEAU, M
    KRIEF, A
    TETRAHEDRON LETTERS, 1984, 25 (33) : 3625 - 3628
  • [3] Catalytic asymmetric synthesis of tertiary alkyl chlorides
    Lee, Elaine C.
    McCauley, Kevin M.
    Fu, Gregory C.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (06) : 977 - 979
  • [4] A NOTE ON THE DECOMPOSITION OF TERTIARY ALKYL PEROXIDES
    GEORGE, P
    WALSH, AD
    TRANSACTIONS OF THE FARADAY SOCIETY, 1946, 42 (1-2): : 94 - 97
  • [5] Catalytic Asymmetric Synthesis of α,α-Difluoromethylated and α-Fluoromethylated Tertiary Alcohols
    Huang, Wei-Sheng
    Delcourt, Marie-Leonie
    Pannecoucke, Xavier
    Charette, Andre B.
    Poisson, Thomas
    Jubault, Philippe
    ORGANIC LETTERS, 2019, 21 (18) : 7509 - 7513
  • [6] REACTIONS OF SILICON PEROXIDES WITH SOME TERTIARY ALCOHOLS
    OLDEKOP, YA
    KHARITON.AN
    AZANOVSKAYA, MM
    ZHURNAL OBSHCHEI KHIMII, 1961, 31 (01): : 126 - &
  • [7] REACTIONS OF SILICON PEROXIDES WITH SOME TERTIARY ALCOHOLS
    OLDEKOP, YA
    AZANOVSKAYA, MM
    KHARITON.AN
    JOURNAL OF GENERAL CHEMISTRY USSR, 1961, 31 (01): : 118 - &
  • [8] Protodeboronation of Tertiary Boronic Esters: Asymmetric Synthesis of Tertiary Alkyl Stereogenic Centers
    Nave, Stefan
    Sonawane, Ravindra P.
    Elford, Tim G.
    Aggarwal, Varinder K.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (48) : 17096 - 17098
  • [9] DECOMPOSITION SYNTHESIS AND KINETICS OF NITROGEN-CONTAINING BIFUNCTIONAL TERTIARY-ALKYL PEROXIDES
    TUROVSKII, AA
    KUCHER, RV
    BATOG, AE
    KIRYUSHI.NP
    ZHURNAL ORGANICHESKOI KHIMII, 1970, 6 (06): : 1227 - +
  • [10] NOVEL APPROACH TO HIGH-YIELD SYNTHESIS OF TERTIARY ALCOHOLS USING ORGANOBORANES
    HUGHES, RJ
    PELTER, A
    SMITH, K
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (21) : 863 - 863
12345