Manganese-catalyzed amination reactions: An overview

被引:5
|
作者
Farzana, Rahim [1 ]
Radhika, Sankaran [1 ]
Saranya, Salim [1 ]
Anilkumar, Gopinathan [1 ,2 ,3 ]
机构
[1] Mahatma Gandhi Univ, Sch Chem Sci, Priyadarsini Hills PO, Kottayam 686560, Kerala, India
[2] Mahatma Gandhi Univ, Adv Mol Mat Res Ctr AMMRC, Kottayam, Kerala, India
[3] Mahatma Gandhi Univ, Inst Integrated Programmes & Res Basic Sci IIRBS, Kottayam, Kerala, India
关键词
amination; catalyst; C-N bond formation; earth abundant; manganese; C-H AMINATION; OXIDATIVE AMINATION; REDUCTIVE AMINATION; EPOXIDATION; ELECTRON; BOND; ACID;
D O I
10.1002/aoc.6421
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
As the nitrogen-containing compounds have broad scope in biological, pharmaceutical, drug delivery, and material science, the C-N bond formation has vital role in synthetic chemistry. To provide a path for the inclusion of nitrogen in organic molecules, a facile establishment of C-N bonds is crucial. Manganese being inexpensive, nontoxic, and earth abundant is found to be a perfect catalyst to carry out amination, instead of using harsh reaction conditions or toxic metal catalysts. Herein, we discuss the manganese-catalyzed amination reactions focusing on various manganese based catalysts for the C-N bond formation and covers the literature until 2020.
引用
收藏
页数:24
相关论文
共 50 条
  • [41] Manganese-catalyzed cross-coupling reactions of nitrogen nucleophiles with aryl halides in water
    Teo, Yong-Chua
    Yong, Fui-Fong
    Poh, Chai-Yun
    Yan, Yaw-Kai
    Chua, Guan-Leong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [42] Manganese-catalyzed cross-coupling reactions of nitrogen nucleophiles with aryl halides in water
    Teo, Yong-Chua
    Yong, Fui-Fong
    Poh, Chai-Yun
    Yan, Yaw-Kai
    Chua, Guan-Leong
    CHEMICAL COMMUNICATIONS, 2009, (41) : 6258 - 6260
  • [43] Manganese-catalyzed asymmetric transfer hydrogenation of hydrazones
    Wang, Lixian
    Lin, Jin
    Xia, Chungu
    Sun, Wei
    JOURNAL OF CATALYSIS, 2022, 413 : 487 - 497
  • [44] A manganese-catalyzed cross-coupling reaction
    Rueping, Magnus
    Ieawsuwan, Winai
    SYNLETT, 2007, (02) : 247 - 250
  • [45] Manganese-catalyzed cyclopropanation of allylic alcohols with sulfones
    Yu, Ke
    Nie, Qin
    Chen, Qianjin
    Liu, Weiping
    NATURE COMMUNICATIONS, 2024, 15 (01)
  • [46] Manganese-catalyzed epoxidations of alkenes in bicarbonate solutions
    Lane, BS
    Vogt, M
    DeRose, VJ
    Burgess, K
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (40) : 11946 - 11954
  • [47] Manganese-Catalyzed Dehydrogenative/Deoxygenative Coupling of Alcohols
    Wang, Yujie
    Liu, Qiang
    SYNLETT, 2020, 31 (15) : 1464 - 1473
  • [48] Manganese-Catalyzed Carboacylations of Alkenes with Alkyl Iodides
    McMahon, Caitlin M.
    Renn, Matthew S.
    Alexanian, Erik J.
    ORGANIC LETTERS, 2016, 18 (16) : 4148 - 4150
  • [49] Manganese-Catalyzed α-Olefination of Nitriles with Secondary Alcohols
    Yadav, Vinita
    Landge, Vinod G.
    Subaramanian, Murugan
    Balaraman, Ekambaram
    ACS CATALYSIS, 2020, 10 (02): : 947 - 954
  • [50] Manganese-Catalyzed Asymmetric Hydrosilylation of Aryl Ketones
    Ma, Xiaochen
    Zuo, Ziqing
    Liu, Guixia
    Huang, Zheng
    ACS OMEGA, 2017, 2 (08): : 4688 - 4692