Manganese-catalyzed cross-coupling reactions of nitrogen nucleophiles with aryl halides in water

被引:32
|
作者
Teo, Yong-Chua [1 ]
Yong, Fui-Fong [1 ]
Poh, Chai-Yun [2 ]
Yan, Yaw-Kai [1 ]
Chua, Guan-Leong [2 ]
机构
[1] Nanyang Technol Univ, Natl Inst Educ, Singapore 637616, Singapore
[2] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
关键词
N BOND FORMATION; GRIGNARD-REAGENTS; FORMING REACTIONS; ALIPHATIC-AMINES; EFFICIENT; ARYLATION; CARBON; ORGANOSTANNANES; COMPLEXES; IODIDES;
D O I
10.1039/b909803h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile and convenient strategy for the assembly of N-arylated heterocycles has been demonstrated using a MnCl2 center dot 4H(2)O/trans-1,2-diaminocyclohexane catalyst and K3PO4 as the base in water.
引用
收藏
页码:6258 / 6260
页数:3
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