Manganese-catalyzed amination reactions: An overview

被引:5
|
作者
Farzana, Rahim [1 ]
Radhika, Sankaran [1 ]
Saranya, Salim [1 ]
Anilkumar, Gopinathan [1 ,2 ,3 ]
机构
[1] Mahatma Gandhi Univ, Sch Chem Sci, Priyadarsini Hills PO, Kottayam 686560, Kerala, India
[2] Mahatma Gandhi Univ, Adv Mol Mat Res Ctr AMMRC, Kottayam, Kerala, India
[3] Mahatma Gandhi Univ, Inst Integrated Programmes & Res Basic Sci IIRBS, Kottayam, Kerala, India
关键词
amination; catalyst; C-N bond formation; earth abundant; manganese; C-H AMINATION; OXIDATIVE AMINATION; REDUCTIVE AMINATION; EPOXIDATION; ELECTRON; BOND; ACID;
D O I
10.1002/aoc.6421
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
As the nitrogen-containing compounds have broad scope in biological, pharmaceutical, drug delivery, and material science, the C-N bond formation has vital role in synthetic chemistry. To provide a path for the inclusion of nitrogen in organic molecules, a facile establishment of C-N bonds is crucial. Manganese being inexpensive, nontoxic, and earth abundant is found to be a perfect catalyst to carry out amination, instead of using harsh reaction conditions or toxic metal catalysts. Herein, we discuss the manganese-catalyzed amination reactions focusing on various manganese based catalysts for the C-N bond formation and covers the literature until 2020.
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页数:24
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