A Simple and Effective Method for α-Hydroxylation of β-Dicarbonyl Compounds Using Oxone as an Oxidant without a Catalyst

被引：46
|
作者：
Yu, Jun [1 ]
Cui, Jian [1 ]
Zhang, Chi [1 ]
机构：
[1] Nankai Univ, State Key Lab Elementoorgan Chem, Res Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 2010卷 / 36期
基金：
中国国家自然科学基金;
关键词：
Synthetic methods; Oxidation; Hydroxylation; Enols; DYE-SENSITIZED PHOTOOXIDATION; 1,3-DICARBONYL COMPOUNDS; OXIDATIVE CLEAVAGE; KETO-ESTERS; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC HYDROXYLATION; BIOMIMETIC SYNTHESIS; SELECTIVE CLEAVAGE; FACILE OXIDATION; SECONDARY-AMINES;
D O I：
10.1002/ejoc.201000940
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxone has been found to be a highly efficient reagent for the introduction of a hydroxy group at the a position of a variety of beta-dicarbonyl compounds in the homogeneous solvent mixture of water and 1,4-dioxane at 60 degrees C.
引用
收藏
页码：7020 / 7026
页数：7
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