A Simple and Effective Method for α-Hydroxylation of β-Dicarbonyl Compounds Using Oxone as an Oxidant without a Catalyst

被引：46
|
作者：
Yu, Jun [1 ]
Cui, Jian [1 ]
Zhang, Chi [1 ]
机构：
[1] Nankai Univ, State Key Lab Elementoorgan Chem, Res Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 2010卷 / 36期
基金：
中国国家自然科学基金;
关键词：
Synthetic methods; Oxidation; Hydroxylation; Enols; DYE-SENSITIZED PHOTOOXIDATION; 1,3-DICARBONYL COMPOUNDS; OXIDATIVE CLEAVAGE; KETO-ESTERS; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC HYDROXYLATION; BIOMIMETIC SYNTHESIS; SELECTIVE CLEAVAGE; FACILE OXIDATION; SECONDARY-AMINES;
D O I：
10.1002/ejoc.201000940
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxone has been found to be a highly efficient reagent for the introduction of a hydroxy group at the a position of a variety of beta-dicarbonyl compounds in the homogeneous solvent mixture of water and 1,4-dioxane at 60 degrees C.
引用
收藏
页码：7020 / 7026
页数：7
相关论文
共 50 条
  • [21] Erratum to: Catalyst-free oxidation of sulfides to sulfoxides and diethylamine catalyzed oxidation of sulfides to sulfones using Oxone as an oxidant
    R. V. Kupwade
    S. S. Khot
    U. P. Lad
    U. V. Desai
    P. P. Wadgaonkar
    Research on Chemical Intermediates, 2018, 44 : 1437 - 1437
  • [22] A simple, novel method for preparing an effective water oxidation catalyst
    Mills, Andrew
    Duckmanton, Paul A.
    Reglinski, John
    CHEMICAL COMMUNICATIONS, 2010, 46 (14) : 2397 - 2398
  • [23] A simple method for α-position deuterated carbonyl compounds with pyrrolidine as catalyst
    Zhan, Miao
    Zhang, Tao
    Huang, Haoxi
    Xie, Yongmei
    Chen, Yuanwei
    JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 2014, 57 (08): : 533 - 539
  • [24] A simple method for the synthesis of tungsten trioxide nanorods array without catalyst
    Zhang, Julan
    Zhang, Gengmin
    Guo, Dengzhu
    Wu, Yue
    Xi, Zhonghe
    SURFACE REVIEW AND LETTERS, 2007, 14 (04) : 607 - 610
  • [25] A simple and low cost method for the synthesis of metallic cobalt nanoparticles without further reduction as an effective catalyst for Fischer–Tropsch Synthesis
    Amir Eshraghi
    Ali Akbar Mirzaei
    Rahbar Rahimi
    Hossein Atashi
    Reaction Kinetics, Mechanisms and Catalysis, 2021, 134 : 127 - 141
  • [26] An unique method for the synthesis of ester compounds without the addition of solvent and catalyst
    Liu, Xinchun
    Zhang, Dan
    Yuan, Yanpeng
    Fu, Jiawei
    Kong, Yuqing
    Sun, Yinyong
    SOLID STATE SCIENCES, 2024, 149
  • [27] A novel and simple method for the silylation of alcohols in DMSO-hexane without a catalyst
    Watahiki, T
    Matsuzaki, M
    Oriyama, T
    GREEN CHEMISTRY, 2003, 5 (01) : 82 - 84
  • [28] A facile and convenient method for deprotection of thiocarbonyls to their carbonyl compounds using oxone under aprotic and nonaqueous conditions
    Mohammadpoor-Baltork, I
    Sadeghi, MM
    Esmayilpour, K
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (01) : 61 - 65
  • [29] A new, efficient method for direct α-alkenylation of β-dicarbonyl compounds and phenols using alkenyltriarylbismuthonium salts
    Matano, Y
    Imahori, H
    JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (16): : 5505 - 5508
  • [30] A simple and low cost method for the synthesis of metallic cobalt nanoparticles without further reduction as an effective catalyst for Fischer-Tropsch Synthesis
    Eshraghi, Amir
    Mirzaei, Ali Akbar
    Rahimi, Rahbar
    Atashi, Hossein
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2021, 134 (01) : 127 - 141
12345