A simple and efficient hydrogenation of benzyl alcohols to methylene compounds using triethylsilane and a palladium catalyst

被引：44

作者：

Mirza-Aghayan, Maryam ^{[1
]}

Boukherroub, Rabah ^{[2
,3
]}

Rahimifard, Mahshid ^{[1
]}

机构：

[1] CCERCI, Tehran, Iran

[2] IRI, USR 3078, F-59652 Villeneuve Dascq, France

[3] IEMN, UMR 8520, F-59652 Villeneuve Dascq, France

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 43期

关键词：

Hydrogenolysis; Benzyl alcohols; Palladium(II) chloride; Triethylsilane; Reduction; Methylene compounds; ARYL KETONES; REDUCTION; SYSTEM; ETHERS; SECONDARY; TERTIARY; HALIDES; ALKANES; OLEFINS; MILD;

D O I：

10.1016/j.tetlet.2009.08.043

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogenolysis of benzyl alcohols using triethylsilane (Et(3)SiH) and a catalytic amount of palladium(II) chloride (PdCl(2)) is described. The reaction takes place under mild conditions affording high yields of the corresponding methylene compounds in short reaction times. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：5930 / 5932

页数：3

共 50 条

[1] Efficient transfer hydrogenation of nitro compounds over a magnetic palladium catalyst
Jiang, Liang
Zhang, Zehui
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (48) : 22983 - 22990
[2] Triethylborane as an efficient promoter for palladium-catalyzed allylation of active methylene compounds with allyl alcohols
Kimura, M
Mukai, R
Tanigawa, N
Tanaka, S
Tamaru, Y
TETRAHEDRON, 2003, 59 (39) : 7767 - 7777
[3] SUSCEPTIBILITY OF PALLADIUM/POLYACRYLONITRILE CATALYST TO POISONING IN HYDROGENATION OF ACETYLENIC ALCOHOLS
TYURENKO.OA
SELIVERS.EI
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR, 1967, 41 (12): : 1684 - &
[4] HYDROGENATION OF ALKYNE ALCOHOLS ON A PALLADIUM/POLY)ETHYLENE TEREPHTHALATE)CATALYST
LANKIN, SF
TYURENKO.OA
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR, 1969, 43 (01): : 76 - &
[5] Easy and partial hydrogenation of aromatic carbonyls to benzyl alcohols using Pd/C(en)-catalyst
Sajiki, H
Hattori, K
Hirota, K
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (24): : 4043 - 4044
[6] More efficient palladium catalyst for hydrogenolysis of benzyl groups
Li, Y
Manickam, G
Ghoshal, A
Subramaniam, P
SYNTHETIC COMMUNICATIONS, 2006, 36 (07) : 925 - 928
[7] Palladium nanoparticles supported on reduced graphene oxide as an efficient catalyst for the reduction of benzyl alcohol compounds
Mirza-Aghayan, Maryam
Tavana, Mandieh Molaee
Boukherroub, Rabah
CATALYSIS COMMUNICATIONS, 2015, 69 : 97 - 103
[8] HYDROGENATION AND ISOMERIZATION OF UNSATURATED-COMPOUNDS ON A PALLADIUM CATALYST
CERVENY, L
LOVYOVA, A
RUZICKA, V
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1980, 45 (12) : 3532 - 3540
[9] Highly efficient and selective hydrogenation of α, β-unsaturated nitriles using supported palladium catalyst
Nitin S. Pagar
Sheetal G. Ingulkar
Journal of the Iranian Chemical Society, 2024, 21 : 913 - 919
[10] Direct Allylation of Active Methylene Compounds with Allylic Alcohols by Use of Palladium/Phosphine-Borane Catalyst System
Shimizu, Aika
Hirata, Goki
Onodera, Gen
Kimura, Masanari
ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (10) : 1954 - 1960

← 1 2 3 4 5 →