A simple and efficient hydrogenation of benzyl alcohols to methylene compounds using triethylsilane and a palladium catalyst

被引：44
|
作者：
Mirza-Aghayan, Maryam [1 ]
Boukherroub, Rabah [2 ,3 ]
Rahimifard, Mahshid [1 ]
机构：
[1] CCERCI, Tehran, Iran
[2] IRI, USR 3078, F-59652 Villeneuve Dascq, France
[3] IEMN, UMR 8520, F-59652 Villeneuve Dascq, France
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 43期
关键词：
Hydrogenolysis; Benzyl alcohols; Palladium(II) chloride; Triethylsilane; Reduction; Methylene compounds; ARYL KETONES; REDUCTION; SYSTEM; ETHERS; SECONDARY; TERTIARY; HALIDES; ALKANES; OLEFINS; MILD;
D O I：
10.1016/j.tetlet.2009.08.043
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hydrogenolysis of benzyl alcohols using triethylsilane (Et(3)SiH) and a catalytic amount of palladium(II) chloride (PdCl(2)) is described. The reaction takes place under mild conditions affording high yields of the corresponding methylene compounds in short reaction times. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5930 / 5932
页数：3
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