A Single Nickel Catalyst for the Acceptorless Dehydrogenation of Alcohols and Hydrogenation of Carbonyl Compounds

被引：111

作者：

Chakraborty, Sumit ^{[1
]}

Piszel, Paige E. ^{[1
]}

Brennessel, William W. ^{[1
]}

Jones, William D. ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 21期

基金：

美国国家科学基金会;

关键词：

IRIDIUM COMPLEXES; OXIDATION; RUTHENIUM; HETEROCYCLES; LIGANDS; IMINES; BEARING; SYSTEM; OSMIUM; WATER;

D O I：

10.1021/acs.organomet.5b00824

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A single homogeneous nickel(II) complex, supported by the tris(3,5-dimethylpyrazoly)borate ligand and 2-hydroxyquinoline ancillary ligand, is shown to catalyze both acceptorless dehydrogenation of alcohols and hydrogenation of carbonyl compounds under mild conditions. Products from the catalytic reactions were isolated with good yields. A mechanistic investigation highlights the critical role of the 2-hydroxyquinoline ligand in the catalysis and argues against a stepwise dehydrogenation pathway.

引用

页码：5203 / 5206

页数：4

共 50 条

[1] Acceptorless Dehydrogenation of Alcohols and Transfer Hydrogenation of Aldehydes in Water Using a Single Bifunctional, Bistate, Water-soluble Ruthenium Catalyst
Hazra, Susanta
Nair, Abhishek
Dolui, Pritam
Malik, Ekta
Elias, Anil J.
CHEMISTRY-AN ASIAN JOURNAL, 2022, 17 (23)
[2] A Molecular Iron Catalyst for the Acceptorless Dehydrogenation and Hydrogenation of N-Heterocycles
Chakraborty, Sumit
Brennessel, William W.
Jones, William D.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (24) : 8564 - 8567
[3] CARBONYLATION OF ALCOHOLS WITH NICKEL CARBONYL CATALYST
ADKINS, H
ROSENTHAL, RW
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (10) : 4550 - 4553
[4] Catalytic Acceptorless Dehydrogenation of Aliphatic Alcohols
Fuse, Hiromu
Mitsunuma, Harunobu
Kanai, Motomu
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (09) : 4493 - 4499
[5] Identification of stable and selective nickel alloy catalyst for acceptorless dehydrogenation of ethane
Li, Guomin
Li, Teng
Wang, Bin
Ding, Yong
Cui, Xinjiang
Shi, Feng
CHINESE JOURNAL OF CATALYSIS, 2025, 70 : 322 - 332
[6] A Reusable Cobalt Catalyst for Reversible Acceptorless Dehydrogenation and Hydrogenation of N-Heterocycles
Jaiswal, Garima
Subaramanian, Murugan
Sahoo, Manoj K.
Balaraman, Ekambaram
CHEMCATCHEM, 2019, 11 (10) : 2449 - 2457
[7] Hydrogenation of carbonylic compounds Part II: The influence of alcohols on the hydrogenation of carbonyl compounds
van Druten, GMR
Ponec, V
APPLIED CATALYSIS A-GENERAL, 2000, 191 (1-2) : 163 - 176
[8] Heterogeneous cobalt catalysts for the acceptorless dehydrogenation of alcohols
Shimizu, Ken-ichi
Kon, Kenichi
Seto, Mayumi
Shimura, Katsuya
Yamazaki, Hiroshi
Kondo, Junko N.
GREEN CHEMISTRY, 2013, 15 (02) : 418 - 424
[9] STUDIES ON CONJUGATED HYDROGENATION - NICKEL CATALYST WITH ALCOHOLS
BASU, HN
CHAKRABARTY, MM
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1966, 43 (03) : 119 - +
[10] Acceptorless dehydrogenation and aerobic oxidation of alcohols with a reusable binuclear rhodium(II) catalyst in water
Wang, Xuewei
Wang, Chao
Liu, Yuxuan
Xiao, Jianliang
GREEN CHEMISTRY, 2016, 18 (17) : 4605 - 4610

← 1 2 3 4 5 →