SET-LRP of acrylates catalyzed by a 1 penny copper coin

被引：26

作者：

Aksakal, R. ^{[1
,2
]}

Resmini, M. ^{[2
]}

Becer, C. R. ^{[1
]}

机构：

[1] Queen Mary Univ London, Sch Mat Sci & Engn, London E1 4NS, England

[2] Queen Mary Univ London, Sch Biol & Chem Sci, London E1 4NS, England

来源：

POLYMER CHEMISTRY | 2016年 / 7卷 / 43期

关键词：

LIVING RADICAL POLYMERIZATION; METHYL-METHACRYLATE; BLOCK-COPOLYMERS; VINYL-CHLORIDE; CU(0); 25-DEGREES-C; POLYMERS; WATER; ATRP; DMSO;

D O I：

10.1039/c6py01295g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A British 1 penny coin (1 p) was used to polymerize a selection of hydrophobic and hydrophilic acrylate monomers using linear and star shaped initiators to obtain polymers even in 50 gram scale with low dispersity values (D = 1.05-1.11). When compared with Cu wire systems, no induction period was observed, hence demonstrating an economic and easily accessible catalyst for SET-LRP acrylates.

引用

页码：6564 / 6569

页数：6

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