SET-LRP of acrylates catalyzed by a 1 penny copper coin

被引：26
|
作者：
Aksakal, R. [1 ,2 ]
Resmini, M. [2 ]
Becer, C. R. [1 ]
机构：
[1] Queen Mary Univ London, Sch Mat Sci & Engn, London E1 4NS, England
[2] Queen Mary Univ London, Sch Biol & Chem Sci, London E1 4NS, England
来源：
POLYMER CHEMISTRY | 2016年 / 7卷 / 43期
关键词：
LIVING RADICAL POLYMERIZATION; METHYL-METHACRYLATE; BLOCK-COPOLYMERS; VINYL-CHLORIDE; CU(0); 25-DEGREES-C; POLYMERS; WATER; ATRP; DMSO;
D O I：
10.1039/c6py01295g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A British 1 penny coin (1 p) was used to polymerize a selection of hydrophobic and hydrophilic acrylate monomers using linear and star shaped initiators to obtain polymers even in 50 gram scale with low dispersity values (D = 1.05-1.11). When compared with Cu wire systems, no induction period was observed, hence demonstrating an economic and easily accessible catalyst for SET-LRP acrylates.
引用
收藏
页码：6564 / 6569
页数：6
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