The Effect of Mixed Ligands on the Polymerization Rate of SET-LRP in Aqueous Solution

被引：0

作者：

Feng, Xiaojing ^{[1
]}

Yuan, Wenxia ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Xueyuan Rd 30th, Beijing 100083, Peoples R China

来源：

CHEMISTRY LETTERS | 2023年 / 52卷 / 12期

关键词：

Mixed-ligand effect; Single electron transfer-living radical polymerization; Aqueous solution; RADICAL POLYMERIZATION; ARYL MESYLATES; PD CATALYST; METHACRYLATE; MIXTURES; CU(0); DMSO;

D O I：

10.1246/cl.230355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mixed-ligand effect is investigated in single electron transfer -living radical polymerization (SET-LRP) of OEOMA in aqueous solution for the first time. Mediated by equimolar tris(2-aminoethyl)amine (TREN) and tris(dimethylaminoethyl)amine (Me6-TREN), SET-LRP exhibits the highest polymerization rate while maintaining living characteristics. The higher concen-tration of self-assembled micellar particles formed by amphi-philic initiator and monomer in aqueous solution under the influence of mixed ligands may be considered as one of factors for the mixed-ligand effect.

引用

页码：865 / 869

页数：5

共 50 条

[1] Synthesis of Zwitterionic Polymer by SET-LRP at Room Temperature in Aqueous
Ding, Wei
Lv, Chongfu
Sun, Ying
Liu, Xiaojun
Yu, Tao
Qu, Guangmiao
Luan, Huoxin
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (02) : 432 - 440
[2] Poly(acrylamides) via SET-LRP in aqueous media: An initiator and ligand investigation
Lloyd, Danielle J.
Haddleton, David M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[3] Synthesis and Aggregation of Double Hydrophilic Diblock Glycopolymers via Aqueous SET-LRP
Zhang, Qiang
Wilson, Paul
Anastasaki, Athina
McHale, Ronan
Haddleton, David M.
ACS MACRO LETTERS, 2014, 3 (05): : 491 - 495
[4] TREN Versus Me6-TREN as Ligands in SET-LRP of Methyl Acrylate
Nguyen, Nga H.
Levere, Martin E.
Percec, Virgil
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (01) : 35 - 46
[5] Grafting of cellulose esters by single electron transfer living radical polymerization Set-LrP
Vlcek, Petr
Raus, Vladimir
Janata, Miroslav
Kriz, Jaroslav
Latalova, Petra
Cadova, Eva
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[6] SET-LRP of Bio- and Petroleum-Sourced Methacrylates in Aqueous Alcoholic Mixtures
Moreno, Adrian
Bensabeh, Nabil
Parve, Jaan
Ronda, Juan C.
Cadiz, Virginia
Galia, Marina
Vares, Lauri
Lligadas, Gerard
Percec, Virgil
BIOMACROMOLECULES, 2019, 20 (04) : 1816 - 1827
[7] Sequence controlled multiblock copolymerisation of acrylamides via aqueous SET-LRP at 0°C
Alsubaie, Fehaid
Haddleton, David M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[8] The Effect of Ligand on the Rate of Propagation of Cu(0) Wire Catalyzed SET-LRP of MA in DMSO at 25 °C
Nguyen, Nga H.
Jiang, Xuan
Fleischmann, Sven
Rosen, Brad M.
Percec, Virgil
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (21) : 5629 - 5638
[9] Absolut "copper catalyzation perfected"; robust living polymerization of NIPAM: Guinness is good for SET-LRP
Waldron, Christopher
Zhang, Qiang
Li, Zaidong
Nikolaou, Vasiliki
Nurumbetov, Gabit
Godfrey, Jamie
McHale, Ronan
Yilmaz, Gokhan
Randev, Rajan K.
Girault, Mony
McEwan, Kayleigh
Haddleton, David M.
Droesbeke, Martijn
Haddleton, Alice J.
Wilson, Paul
Simula, Alexandre
Collins, Jennifer
Lloyd, Danielle J.
Burns, James A.
Summers, Christopher
Houben, Claudia
Anastasaki, Athina
Li, Muxiu
Becer, C. Remzi
Kiviaho, Jenny K.
Risangud, Nuttapol
POLYMER CHEMISTRY, 2014, 5 (01) : 57 - 61
[10] Copper(0)-Mediated Living Radical Polymerization of Acrylonitrile: SET-LRP or AGET-ATRP
Liu, Xiao-Hui
Zhang, Gui-Bao
Li, Bai-Xiang
Bai, Yun-Gang
Li, Yue-Sheng
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (23) : 5439 - 5445

← 1 2 3 4 5 →