The Effect of Mixed Ligands on the Polymerization Rate of SET-LRP in Aqueous Solution

被引：0
|
作者：
Feng, Xiaojing [1 ]
Yuan, Wenxia [1 ]
机构：
[1] Univ Sci & Technol Beijing, Xueyuan Rd 30th, Beijing 100083, Peoples R China
来源：
CHEMISTRY LETTERS | 2023年 / 52卷 / 12期
关键词：
Mixed-ligand effect; Single electron transfer-living radical polymerization; Aqueous solution; RADICAL POLYMERIZATION; ARYL MESYLATES; PD CATALYST; METHACRYLATE; MIXTURES; CU(0); DMSO;
D O I：
10.1246/cl.230355
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The mixed-ligand effect is investigated in single electron transfer -living radical polymerization (SET-LRP) of OEOMA in aqueous solution for the first time. Mediated by equimolar tris(2-aminoethyl)amine (TREN) and tris(dimethylaminoethyl)amine (Me6-TREN), SET-LRP exhibits the highest polymerization rate while maintaining living characteristics. The higher concen-tration of self-assembled micellar particles formed by amphi-philic initiator and monomer in aqueous solution under the influence of mixed ligands may be considered as one of factors for the mixed-ligand effect.
引用
收藏
页码：865 / 869
页数：5
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