Synthesis of 3-Sulfonyl Indenones via Copper-Catalyzed Redox-Neutral Coupling Reaction

被引：0

作者：

Huang, Yuan ^{[1
]}

Chen, Dengfeng ^{[1
]}

Zheng, Yu ^{[1
]}

Huang, Shenlin ^{[1
]}

机构：

[1] Nanjing Forestry Univ, Int Innovat Ctr Forest Chem & Mat, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Nanjing 210037, Peoples R China

来源：

CHEMISTRYSELECT | 2022年 / 7卷 / 05期

基金：

中国博士后科学基金;

关键词：

Copper; Cross-coupling; Indenones; Oximes; Radical reactions; UNSYMMETRICAL NONSTEROIDAL LIGANDS; OXIME ACETATES; BINDING ORIENTATION; EFFICIENT SYNTHESIS; 2-ARYLINDENONES; STRATEGY; DESIGN; ACCESS; ROUTE; RING;

D O I：

10.1002/slct.202104347

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to C-C bond cleavage of cyclic oxime esters, the corresponding coupling reaction without ring-opening are less explored. In this context, we report an unprecedented method for the synthesis of 3-sulfonyl indenones via copper-catalyzed redox-neutral coupling reaction of indanone derivatives with sodium sulfinates. This approach provides an efficient approach to 3-sulfonyl indenones from readily available indanone derivatives without any ligands and external oxidants.

引用

页数：4

共 50 条

[41] By-Product-Catalyzed Redox-Neutral Sulfenylation/Deiodination/Aromatization of Cyclic Alkenyl Iodides with Sulfonyl Hydrazides
Yang, Fu-Lai
Gui, Yang
Yu, Bang-Kui
Jin, You-Xiang
Tian, Shi-Kai
ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (21) : 3368 - 3372
[42] Microwave-Assisted Copper-Catalyzed Coupling of Bromoalkynes and Sulfonamides: Rapid Synthesis of N -Sulfonyl Ynamides
Hong, Su Jeong
Lee, Joon-Ho
Yeom, Hyun-Suk
SYNLETT, 2024, 35 (12) : 1436 - 1440
[43] Synthesis of benzofurans via ruthenium-catalyzed redox-neutral C-H functionalization and reaction with alkynes under mild conditions
Zhou, Zhi
Liu, Guixia
Shen, Yangyang
Lu, Xiyan
Organic Chemistry Frontiers, 2014, 1 (10): : 1161 - 1165
[44] Synthesis of β- and γ-carbolines by the palladium/copper-catalyzed coupling and copper-catalyzed or thermal cyclization of terminal acetylenes
Zhang, HM
Larock, RC
TETRAHEDRON LETTERS, 2002, 43 (08) : 1359 - 1362
[45] Cobalt(III)-Catalyzed Redox-Neutral Coupling of Acrylamides with Activated Alkenes via C-H Bond Activation
Keerthana, Meledath Sudhakaran
Manoharan, Ramasamy
Jeganmohan, Masilamani
SYNTHESIS-STUTTGART, 2020, 52 (11): : 1625 - 1633
[46] Cobalt(III)-Catalyzed Intermolecular Carboamination of Propiolates and Bicyclic Alkenes via Non-Annulative Redox-Neutral Coupling
Zhu, Yuelu
Chen, Feng
Zhao, Xinyang
Yan, Dingyuan
Yong, Wanxiong
Zhao, Jing
ORGANIC LETTERS, 2019, 21 (15) : 5884 - 5888
[47] Atom economic macrolactonization and lactonization via redox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids
Lumbroso, Alexandre
Abermil, Nacim
Breit, Bernhard
CHEMICAL SCIENCE, 2012, 3 (03) : 789 - 793
[48] Synthesis of Functionalized Quinazolinones via Acid-Catalyzed Redox Neutral Reaction
Mondal, Mohabul A.
Mondal, Sudipta
Khan, Abdul A.
CHEMISTRYSELECT, 2021, 6 (42): : 11788 - 11791
[49] Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate
Doi, Ryohei
Ohashi, Masato
Ogoshi, Sensuke
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (01) : 341 - 344
[50] Practical synthesis of C-aryl glycosides via redox-neutral Borono-Catellani reaction
Xu, Dekang
Li, Xia
Cui, Ziyang
Cao, Liming
Cheng, Hong-Gang
Zhou, Qianghui
CHEMICAL COMMUNICATIONS, 2025, 61 (04) : 736 - 739

← 1 2 3 4 5 →