Practical synthesis of C-aryl glycosides via redox-neutral Borono-Catellani reaction

被引：1

作者：

Xu, Dekang ^{[1
,2
,3
]}

Li, Xia ^{[1
,2
,3
]}

Cui, Ziyang ^{[1
,2
,3
]}

Cao, Liming ^{[1
,2
,3
]}

Cheng, Hong-Gang ^{[1
,2
,3
]}

Zhou, Qianghui ^{[1
,2
,3
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Sauvage Ctr Mol Sci, Hubei Key Lab Organ & Polymer Optoelect Mat,Engn R, Wuhan 430072, Peoples R China

[2] Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China

[3] Wuhan Univ, TaiKang Ctr Life & Med Sci, Wuhan 430072, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 04期

关键词：

GLYCOSYLATION; NUCLEOPHILES;

D O I：

10.1039/d4cc05665e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we describe a practical Borono-Catellani strategy for the efficient synthesis of C-aryl glycosides, with readily available arylboronic esters and glycosyl chlorides as the building blocks. It features mild reaction conditions, excellent diastereoselectivities, and good functional group tolerance. A diverse array of highly decorated C-(hetero)aryl glycosides are obtained in a convergent and redox-neutral manner.

引用

页码：736 / 739

页数：4

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