Practical synthesis of C-aryl glycosides via redox-neutral Borono-Catellani reaction

被引：1
|
作者：
Xu, Dekang [1 ,2 ,3 ]
Li, Xia [1 ,2 ,3 ]
Cui, Ziyang [1 ,2 ,3 ]
Cao, Liming [1 ,2 ,3 ]
Cheng, Hong-Gang [1 ,2 ,3 ]
Zhou, Qianghui [1 ,2 ,3 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Sauvage Ctr Mol Sci, Hubei Key Lab Organ & Polymer Optoelect Mat,Engn R, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China
[3] Wuhan Univ, TaiKang Ctr Life & Med Sci, Wuhan 430072, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 04期
关键词：
GLYCOSYLATION; NUCLEOPHILES;
D O I：
10.1039/d4cc05665e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we describe a practical Borono-Catellani strategy for the efficient synthesis of C-aryl glycosides, with readily available arylboronic esters and glycosyl chlorides as the building blocks. It features mild reaction conditions, excellent diastereoselectivities, and good functional group tolerance. A diverse array of highly decorated C-(hetero)aryl glycosides are obtained in a convergent and redox-neutral manner.
引用
收藏
页码：736 / 739
页数：4
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