Synthesis of 3-Sulfonyl Indenones via Copper-Catalyzed Redox-Neutral Coupling Reaction

被引：0

作者：

Huang, Yuan ^{[1
]}

Chen, Dengfeng ^{[1
]}

Zheng, Yu ^{[1
]}

Huang, Shenlin ^{[1
]}

机构：

[1] Nanjing Forestry Univ, Int Innovat Ctr Forest Chem & Mat, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Nanjing 210037, Peoples R China

来源：

CHEMISTRYSELECT | 2022年 / 7卷 / 05期

基金：

中国博士后科学基金;

关键词：

Copper; Cross-coupling; Indenones; Oximes; Radical reactions; UNSYMMETRICAL NONSTEROIDAL LIGANDS; OXIME ACETATES; BINDING ORIENTATION; EFFICIENT SYNTHESIS; 2-ARYLINDENONES; STRATEGY; DESIGN; ACCESS; ROUTE; RING;

D O I：

10.1002/slct.202104347

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to C-C bond cleavage of cyclic oxime esters, the corresponding coupling reaction without ring-opening are less explored. In this context, we report an unprecedented method for the synthesis of 3-sulfonyl indenones via copper-catalyzed redox-neutral coupling reaction of indanone derivatives with sodium sulfinates. This approach provides an efficient approach to 3-sulfonyl indenones from readily available indanone derivatives without any ligands and external oxidants.

引用

页数：4

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