Synthesis and photophysical properties of a ruthenium(II) complex as a precursor of water oxidation catalysts

被引:0
|
作者
Kong, Jianfei [1 ]
Zhang, Qi [1 ]
Yang, Hengyue [1 ]
机构
[1] Jiangsu Vocat Coll Med, 283 Jiefang Southern Rd, Yancheng 224005, Jiangsu, Peoples R China
来源
PRZEMYSL CHEMICZNY | 2021年 / 100卷 / 08期
关键词
D O I
10.15199/62.2021.8.11
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A mononuclear [Ru(bpy)(2)-N boolean AND N] complex where bpy is 2,2'-bipyridine and N boolean AND N is 6,7-dimethyl-2,3-di(2-pyridyl) quinoxaline was synthesized and studied for electronic absorption, luminescence, electrochem. properties and catalytic activity in O evolution reactions (OER) after addn. of an extra equiv. of Ru(II) ion. The so-formed binuclear Ru [Ru(bpy)(2)-N boolean AND N-Ru] complex showed a greatly enhanced catalytic activity in OER.
引用
收藏
页码:775 / 780
页数:6
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