Synthesis and photophysical properties of a ruthenium(II) complex as a precursor of water oxidation catalysts

被引：0
|
作者：
Kong, Jianfei [1 ]
Zhang, Qi [1 ]
Yang, Hengyue [1 ]
机构：
[1] Jiangsu Vocat Coll Med, 283 Jiefang Southern Rd, Yancheng 224005, Jiangsu, Peoples R China
来源：
PRZEMYSL CHEMICZNY | 2021年 / 100卷 / 08期
关键词：
D O I：
10.15199/62.2021.8.11
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mononuclear [Ru(bpy)(2)-N boolean AND N] complex where bpy is 2,2'-bipyridine and N boolean AND N is 6,7-dimethyl-2,3-di(2-pyridyl) quinoxaline was synthesized and studied for electronic absorption, luminescence, electrochem. properties and catalytic activity in O evolution reactions (OER) after addn. of an extra equiv. of Ru(II) ion. The so-formed binuclear Ru [Ru(bpy)(2)-N boolean AND N-Ru] complex showed a greatly enhanced catalytic activity in OER.
引用
收藏
页码：775 / 780
页数：6
相关论文
共 50 条
  • [31] Synthesis, photophysical, and electrochemical properties of two polynuclear ruthenium(II) polypyridyl complexes containing diazafluorene
    Cheng, Feixiang
    Chen, Jishu
    Wang, Fan
    Tang, Ning
    Chen, Longhai
    TRANSITION METAL CHEMISTRY, 2011, 36 (05) : 573 - 578
  • [32] Synthesis, photophysical, and electrochemical properties of two polynuclear ruthenium(II) polypyridyl complexes containing diazafluorene
    Feixiang Cheng
    Jishu Chen
    Fan Wang
    Ning Tang
    Longhai Chen
    Transition Metal Chemistry, 2011, 36 : 573 - 578
  • [33] SYNTHESIS AND PHOTOPHYSICAL PROPERTIES OF MONO(2,2',2''TERPYRIDINE) COMPLEXES OF RUTHENIUM(II)
    COE, BJ
    THOMPSON, DW
    CULBERTSON, CT
    SCHOONOVER, JR
    MEYER, TJ
    INORGANIC CHEMISTRY, 1995, 34 (13) : 3385 - 3395
  • [34] Synthesis and Photophysical Properties of Ruthenium(II) Isocyanide Complexes Containing 8-Quinolinolate Ligands
    Leung, Chi-Fai
    Ng, Siu-Mui
    Xiang, Jing
    Wong, Wai-Yeung
    Lam, Michael Hon-Wah
    Ko, Chi-Chiu
    Lau, Tai-Chu
    ORGANOMETALLICS, 2009, 28 (19) : 5709 - 5714
  • [35] ELECTROCHEMICAL AND PHOTOPHYSICAL PROPERTIES OF MONOMETALLIC AND BIMETALLIC RUTHENIUM(II) COMPLEXES
    WALLACE, AW
    MURPHY, WR
    PETERSEN, JD
    INORGANICA CHIMICA ACTA, 1989, 166 (01) : 47 - 54
  • [36] Ruthenium Water Oxidation Catalysts based on Pentapyridyl Ligands
    Gil-Sepulcre, Marcos
    Bohler, Michael
    Schilling, Mauro
    Bozoglian, Fernando
    Bachmann, Cyril
    Scherrer, Dominik
    Fox, Thomas
    Spingler, Bernhard
    Gimbert-Surinach, Carolina
    Alberto, Roger
    Bofill, Roger
    Sala, Xavier
    Luber, Sandra
    Richmond, Craig J.
    Llobet, Antoni
    CHEMSUSCHEM, 2017, 10 (22) : 4517 - 4525
  • [37] Durable ruthenium oxide catalysts for water oxidation reaction
    Jiao, Jixiang
    Chen, Ding
    Zhao, Hongyu
    Dong, Ying
    Mu, Shichun
    SCIENCE CHINA-CHEMISTRY, 2024,
  • [38] PHOTOPHYSICAL PROPERTIES OF BIS-PYRIDINE RUTHENIUM(II) HETEROCYCLES
    RILLEMA, DP
    BOLDAJI, M
    WORL, L
    MEYER, TJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 515 - INOR
  • [39] Photophysical properties of ruthenium(II) polyazaaromatic compounds:: A theoretical insight
    Pourtois, G
    Beljonne, D
    Moucheron, C
    Schumm, S
    Kirsch-De Mesmaeker, A
    Lazzaroni, R
    Brédas, JL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) : 683 - 692
  • [40] MONONUCLEAR RUTHENIUM AMMINE COMPLEXES AS CATALYSTS FOR WATER OXIDATION
    RAMARAJ, R
    KIRA, A
    KANEKO, M
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) : 227 - 228
12345