Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex

被引：38
|
作者：
Browne, WR
O'Connor, CM
Villani, C
Vos, JG [1 ]
机构：
[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland
[2] Univ G dAnnunzio, Dipartimento Sci Farmaco, I-66013 Chieti, Italy
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 21期
关键词：
D O I：
10.1021/ic010473m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The separation of the four stereoisomers of [(Ru(boy)2)2(bpt)](PF6)3 (where bpy=2,2′-bipyridine, Hbpt=3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semi-preparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.
引用
收藏
页码：5461 / 5464
页数：4
相关论文
共 50 条
  • [1] Redox properties of a bipyrimidine-bridged dinuclear ruthenium(II) complex
    Ishizuka, Tomoya
    Itogawa, Masaki
    Shimomura, Hinatsu
    Shiota, Yoshihito
    Kotani, Hiroaki
    Yoshizawa, Kazunari
    Kojima, Takahiko
    INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 120
  • [2] Photophysical properties of a ruthenium(II) phthalocyanine
    Guez, D
    Markovitsi, D
    Sommerauer, M
    Hanack, M
    CHEMICAL PHYSICS LETTERS, 1996, 249 (5-6) : 309 - 313
  • [3] Synthesis and photophysical properties of a ruthenium(II) complex as a precursor of water oxidation catalysts
    Kong, Jianfei
    Zhang, Qi
    Yang, Hengyue
    PRZEMYSL CHEMICZNY, 2021, 100 (08): : 775 - 780
  • [4] Crystal structure, physical, and photophysical properties of a ruthenium(II) bipyridine diazafluorenone complex
    Wang, YX
    Jackman, DC
    Woods, C
    Rillema, DP
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1995, 25 (09) : 549 - 553
  • [5] PHOTOPHYSICAL PROPERTIES OF A DINUCLEAR RACK-TYPE RU(II) COMPLEX AND OF ITS COMPONENTS
    CREDI, A
    BALZANI, V
    CAMPAGNA, S
    HANAN, GS
    ARANA, CR
    LEHN, JM
    CHEMICAL PHYSICS LETTERS, 1995, 243 (1-2) : 102 - 107
  • [6] Molecular recognition and photo-electron transfer between the stereoisomers of a dinuclear ruthenium(II) complex and mono- and polynucleotides
    Brodkorb, A
    Keene, R
    Kirsch-De Mesmaeker, A
    SPECTROSCOPY OF BIOLOGICAL MOLECULES: NEW DIRECTIONS, 1999, : 225 - 226
  • [7] Intervalence charge transfer in the stereoisomers of a dinuclear ruthenium complex containing the bridging ligand dibenzoeilatin
    D'Alessandro, DM
    Keene, FR
    Bergman, SD
    Kol, M
    DALTON TRANSACTIONS, 2005, (02) : 332 - 337
  • [8] Electronic and photophysical properties of a novel phenol bound dinuclear ruthenium complex: evidence for a luminescent mixed valence state
    Keyes, TE
    Evrard, B
    Vos, JG
    Brady, C
    McGarvey, JJ
    Jayaweera, P
    DALTON TRANSACTIONS, 2004, (15) : 2341 - 2346
  • [9] SYNTHESIS, PHOTOPHYSICAL, ELECTROCHEMICAL AND DNA BINDING PROPERTIES OF A NOVEL RUTHENIUM(II) NN COMPLEX
    Kong, Jianfei
    Chen, Jun
    Jiang, Liying
    REVUE ROUMAINE DE CHIMIE, 2019, 64 (04) : 335 - +
  • [10] PHOTOPHYSICAL PROPERTIES OF MONOMERIC AND OLIGOMERIC RUTHENIUM(II) PORPHYRINS
    IKONEN, M
    GUEZ, D
    MARVAUD, V
    MARKOVITSI, D
    CHEMICAL PHYSICS LETTERS, 1994, 231 (01) : 93 - 97
12345