Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex

被引：38
|
作者：
Browne, WR
O'Connor, CM
Villani, C
Vos, JG [1 ]
机构：
[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland
[2] Univ G dAnnunzio, Dipartimento Sci Farmaco, I-66013 Chieti, Italy
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 21期
关键词：
D O I：
10.1021/ic010473m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The separation of the four stereoisomers of [(Ru(boy)2)2(bpt)](PF6)3 (where bpy=2,2′-bipyridine, Hbpt=3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semi-preparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.
引用
收藏
页码：5461 / 5464
页数：4
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