A tetracarboxylatobenzene-bridged binuclear copper(II) complex

被引：16
|
作者：
Chen, W [1 ]
Tioh, NH [1 ]
Zu, JZ [1 ]
Xu, Z [1 ]
You, XZ [1 ]
机构：
[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270195010444
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The tetracarboxylatobenzene tetraanion in mu-(1,2,4,5-benzenetetracarboxylato-O-1:O-4)bis[aqua(4-azaheptane- 1,7-diamine-N,N',N '')copper(II)] octahydrate, [{Cu-(C6H17N3)(H2O)}(2)(mu-C10H2O8)].8H(2)O, bridges two N,N',N ''-chelated aquacopper entities in a monodentate manner to give rise to square-pyramidal coordination at the metal centres. Hydrogen bonding involving the three N atoms, the four carboxyl O atoms and the five water molecules gives rise to a three-dimensional network structure.
引用
收藏
页码：43 / 45
页数：3
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