A tetracarboxylatobenzene-bridged binuclear copper(II) complex

被引：16

作者：

Chen, W ^{[1
]}

Tioh, NH ^{[1
]}

Zu, JZ ^{[1
]}

Xu, Z ^{[1
]}

You, XZ ^{[1
]}

机构：

[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195010444

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetracarboxylatobenzene tetraanion in mu-(1,2,4,5-benzenetetracarboxylato-O-1:O-4)bis[aqua(4-azaheptane- 1,7-diamine-N,N',N '')copper(II)] octahydrate, [{Cu-(C6H17N3)(H2O)}(2)(mu-C10H2O8)].8H(2)O, bridges two N,N',N ''-chelated aquacopper entities in a monodentate manner to give rise to square-pyramidal coordination at the metal centres. Hydrogen bonding involving the three N atoms, the four carboxyl O atoms and the five water molecules gives rise to a three-dimensional network structure.

引用

页码：43 / 45

页数：3

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