A tetracarboxylatobenzene-bridged binuclear copper(II) complex

被引:16
|
作者
Chen, W [1 ]
Tioh, NH [1 ]
Zu, JZ [1 ]
Xu, Z [1 ]
You, XZ [1 ]
机构
[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA
关键词
D O I
10.1107/S0108270195010444
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The tetracarboxylatobenzene tetraanion in mu-(1,2,4,5-benzenetetracarboxylato-O-1:O-4)bis[aqua(4-azaheptane- 1,7-diamine-N,N',N '')copper(II)] octahydrate, [{Cu-(C6H17N3)(H2O)}(2)(mu-C10H2O8)].8H(2)O, bridges two N,N',N ''-chelated aquacopper entities in a monodentate manner to give rise to square-pyramidal coordination at the metal centres. Hydrogen bonding involving the three N atoms, the four carboxyl O atoms and the five water molecules gives rise to a three-dimensional network structure.
引用
收藏
页码:43 / 45
页数:3
相关论文
共 50 条
  • [31] A sugar discriminating binuclear copper(II) complex
    Striegler, S. (susanne.striegler@chemie.uni-ulm.de), 1600, American Chemical Society (125):
  • [32] A COBALT(III) COPPER(II) BINUCLEAR COMPLEX
    CROOK, BV
    DOINE, H
    STEPHENS, FF
    CANNON, MJ
    CANNON, RD
    POLYHEDRON, 1989, 8 (15) : 2007 - 2009
  • [33] PREPARATION AND SPECTRAL, MAGNETIC, AND ELECTROCHEMICAL CHARACTERIZATION OF A FLEXIBLE PHENOXO-BRIDGED BINUCLEAR COPPER(II) COMPLEX
    MAZUREK, W
    BOND, AM
    MURRAY, KS
    OCONNOR, MJ
    WEDD, AG
    INORGANIC CHEMISTRY, 1985, 24 (16) : 2484 - 2490
  • [34] Magnetic properties of diphosphonate-bridged binuclear copper(II) complex: a density functional theory study
    Hu, ZC
    Wei, HY
    Chen, ZD
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2004, 668 (2-3): : 235 - 242
  • [35] Synthesis and structure of a novel bridged binuclear zinc(II) complex
    Liu, XL
    Zhao, R
    Liu, XH
    Yue, JJ
    Chen, K
    Miao, FM
    ACTA CHIMICA SINICA, 2003, 61 (04) : 578 - 583
  • [36] Synthesis, magnetic and spectral properties of binuclear imidazolate bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes
    Patel, RN
    Patel, AP
    Pandeya, KB
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2001, 78 (01) : 6 - 8
  • [37] Synthesis,structure and properties of an imidazolate bridged copper,zinc binuclear complex
    MAO
    CHEN
    TANG
    LIU
    Chinese Journal of Chemistry, 1992, (01) : 45 - 51
  • [38] DOUBLY BRIDGED BINUCLEAR COPPER(II) COMPLEXES WITH DISSIMILAR BRIDGING ATOMS
    OCONNOR, CJ
    SORRELL, TN
    BOILLOT, ML
    KAHN, O
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-): : 258 - INOR
  • [39] EXAFS study of binuclear hydroxo-bridged copper(II) complexes
    Gaur, Abhijeet
    Shrivastava, B. D.
    Gaur, D. C.
    Prasad, J.
    Srivastava, K.
    Jha, S. N.
    Bhattacharyya, D.
    Poswal, A.
    Deb, S. K.
    JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (07) : 1265 - 1275
  • [40] ANTIFERROMAGNETIC BINUCLEAR HALOGEN-BRIDGED DITHIOCARBAMATE COMPLEXES OF COPPER(II)
    FURNEAUX, RH
    SINN, E
    INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1976, 12 (06): : 501 - 503