First example of linear strings of equidistant gold atoms in crystals of [(2,4,6-Me3C6H2NC)(2)Au] [Au(GeCl3)(2)]

被引：23

作者：

Bauer, A ^{[1
]}

Schneider, W ^{[1
]}

Schmidbaur, H ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 10期

关键词：

D O I：

10.1021/ic9701468

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Insertion of GeCl2 into the Au-Cl bond of (mesityl isocyanide)gold(I) chloride, followed by a ligand redistribution, leads to the title compound, which crystallizes in strings of alternating cations and anions with linear chains of equidistant gold atoms (Au1-Au2 = 3.435 Angstrom).

引用

页码：2225 / &

页数：3

共 50 条

[41] Compounds containing λ3,σ2-Sb=C bonds:: synthesis and structural characterisation of the first stiba-enol, Mes*C(O)Sb=C(OH)Mes* (Mes* = C6H2But3-2,4,6) and a 2,3-distibabutadiene, {Mes(Me3SiO)C=Sb}2 (mes = C6H2Me3-2,4,6)
Jones, C
Steed, JW
Thomas, RC
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (10): : 1541 - 1542
[42] Synthesis and characterization of the organoiodocuprate complexes [Li(THF)4][2,6-Mes2H3C6Cu2I2] (Mes = C6H2-2,4,6-Me3) and (Et2O)2Li[ICuC6H3-2,6-Trip2} (Trip = C6H2-2,4,6-i-Pr3)
Hwang, CS
Power, PP
ORGANOMETALLICS, 1999, 18 (04) : 697 - 700
[43] Complexes of N-Phosphorylated Thioureas RNHC(S)NHP(O)(OiPr)2 (R=2-MeC6H4, 2,6-Me2C6H3, 2,4,6-Me3C6H2) With Nickel(II)
Safin, Damir A.
Babashkina, Maria G.
Bolte, Michael
Klein, Axel
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (12) : 2426 - 2432
[44] Metallic system with aromatic character. Synthesis and molecular structure of Na2[(Mes2C6H3)Ga]3 (Mes -2,4,6-Me3C6H2). The first cyclogallane
Li, X.-W.
Pennington, W.T.
Robinson, G.H.
1995, ACS, Washington, DC, USA (117)
[45] Sr2Au6Al3 and Eu2Au6Al3 - First Representatives of the Sr2Au6Zn3 Type with Aluminum Triangles
Gerke, Birgit
Poettgen, Rainer
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2014, 69 (01): : 121 - 124
[46] Synthesis and reactivity of alkyl, hydride, and silyl derivatives of the (terphenyl)imido fragments Cp*(ArMesN=)Ta (Cp* = η5-C5Me5;: ArMes=2,6-(2,4,6-Me3C6H2)2C6H3) and Cp*(ArTripN=)Ta (ArTrip=2,6-(2,4,6-iPr3C6H2)2C6H3)
Gavenonis, J
Tilley, TD
ORGANOMETALLICS, 2004, 23 (01) : 31 - 43
[47] AURIOPHILICITY IN POLYNUCLEAR (PHOSPHANE)GOLD(I) THIOLATES (ME(3)CS[AU(PPH(3))](2))(+) BF4- AND ((CH2S)(2)[AU(PPH(3))](3))(+) BF4-
SLADEK, A
SCHMIDBAUR, H
CHEMISCHE BERICHTE-RECUEIL, 1995, 128 (09): : 907 - 909
[48] CHLORO (ARYLOXY/ALKOXY) GALLIUM COMPOUNDS - SYNTHESIS AND STRUCTURE OF (2,4,6-ME(3)C(6)H(2)O)(2)GACL-CENTER-DOT-TBUNH(2), (2,6-(TBU)(2)-4-(ME)C6H2O)GACL2-CENTER-DOT-OET(2) AND [TBUNH(3)]+ [(CL3GA)(2)O-2,4,6-ME(3)C(6)H(2)]-+
SWAMY, KK
VEITH, M
HUCH, V
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1995, 132 (5-6): : 540 - 544
[49] INCLUSION AND AGGREGATION PROPERTIES OF ORGANOGOLD COMPLEXES - CRYSTAL-STRUCTURES OF C2(AU[P(C6H4R-3)3])2.NC6H6(R = H, N = 2-R = ME, N = 0 AND 1)
BRUCE, MI
GRUNDY, KR
LIDDELL, MJ
SNOW, MR
TIEKINK, ERT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 344 (03) : C49 - C52
[50] Synthesis and crystal structure of dinuclear [(thf)3YCl2{μ-P(H)C6H2-2,4,6-Me3}]2 with seven-coordinate yttrium atoms
Krieck, Sven
Goerls, Helmar
Westerhausen, Matthias
INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (05) : 409 - 411

← 1 2 3 4 5 →