First example of linear strings of equidistant gold atoms in crystals of [(2,4,6-Me3C6H2NC)(2)Au] [Au(GeCl3)(2)]

被引：23

作者：

Bauer, A ^{[1
]}

Schneider, W ^{[1
]}

Schmidbaur, H ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 10期

关键词：

D O I：

10.1021/ic9701468

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Insertion of GeCl2 into the Au-Cl bond of (mesityl isocyanide)gold(I) chloride, followed by a ligand redistribution, leads to the title compound, which crystallizes in strings of alternating cations and anions with linear chains of equidistant gold atoms (Au1-Au2 = 3.435 Angstrom).

引用

页码：2225 / &

页数：3

共 50 条

[31] Synthesis and characterization of monomeric organogallium-nitrogen compounds, Et2GaNMe[C6H2(2,4,6-t-Bu)3], Me2GaNMe[C6H2(2,4,6-t-Bu)3], MeGa{NH[C6H2(2,4,6-t-Bu)3]}2, and Ga{NH[C6H2(2,4,6-t-Bu)3]}3
Beachley, OT
Rosenblum, DB
MacRae, DJ
ORGANOMETALLICS, 2001, 20 (05) : 945 - 949
[32] TERT-BUTYLIMIDO AND TERT-BUTYLIMIDO OXO ARYLS OF RHENIUM - X-RAY CRYSTAL-STRUCTURES OF RE(NBUTERT)2(2,6-ME2C6H3)2, RE(NBUTERT)(2,4,6-ME3C6H2)(C27H32), RE(NBUTERT)3(2,4,6-ME3C6H2), [(BUTERTN)BR(2,4,6-ME3C6H2)RE(MU-NBUTERT)(MU-O)RE(OC6H2ME2CH2)(NBUTERT)], [RE(NBUTERT)(O)AR(MU-O)]2, AR = 2,6-C6H3 AND 2,4,6-C6H2
GUTIERREZ, A
WILKINSON, G
HUSSAINBATES, B
HURSTHOUSE, MB
POLYHEDRON, 1990, 9 (17) : 2081 - 2096
[33] Crystal structure of 2-mercapto-2-thiazoline(triphenylphosphine)-gold(I), [Au(C3H4NS2)P(C6H5)(3)]
Grant, TA
Forward, JM
Fackler, JP
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (07): : 483 - 484
[34] [Au(2-C2H4)3]+[Al(ORF)4] a Stable Homoleptic (Ethene)gold Complex
Schaefer, Julia
Himmel, Daniel
Krossing, Ingo
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (15) : 2712 - 2717
[35] Preparation and structures of arylmolybdenum(6+) nitrido compounds. (2,4,6-Me3C6H2)3Mo=N and (2-Me2NCH2-C6H4)2(tBuO)Mo=N
Caulton, K.G.
Chisholm, M.H.
Doherty, S.
Folting, K.
Organometallics, 1995, 14 (05)
[36] A METALLIC SYSTEM WITH AROMATIC CHARACTER - SYNTHESIS AND MOLECULAR-STRUCTURE OF NA-2[(MES(2)C(6)H(3))GA](3) (MES=2,4,6-ME(3)C(6)H(2)) - THE FIRST CYCLOGALLANE
LI, XW
PENNINGTON, WT
ROBINSON, GH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (28) : 7578 - 7579
[37] TRANSITION-METAL FUNCTIONALIZED PHOSPHAARSENES (ETA-5-C5H4H)-(CO)(PPH3)FE-AS=P-C6H2(TBU)3(2,4,6), (ETA-5-C5H4ME)-(CO)(PPH3)FE-AS=P-C6H2(TBU)3(2,4,6) AND 1,3,2,4-DIPHOSPHADIARSETANES [(ETA-5-C5ME5)(CO)2FE-AS-P-C6H2ME3(2,4,6)]2
WEBER, L
BUNGARDT, D
BOESE, R
BLASER, D
CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (06): : 1033 - 1038
[38] Synthesis and characterization of N-phosphorylated thioureas RNHC(S)NHP(O)(OiPr)2 (R = 2-MeC6H4, 2,6-Me2C6H3, 2,4,6-Me2C6H3)
Damir A. Safin
Maria G. Babashkina
Michael Bolte
Axel Klein
Journal of Chemical Sciences, 2010, 122 : 409 - 413
[39] Synthesis and characterization of N-phosphorylated thioureas RNHC(S)NHP(O)(OiPr)2 (R=2-MeC6H4, 2,6-Me2C6H3, 2,4,6-Me3C6H2)
Safin, Damir A.
Babashkina, Maria G.
Bolte, Michael
Klein, Axel
JOURNAL OF CHEMICAL SCIENCES, 2010, 122 (03) : 409 - 413
[40] PREPARATION AND STRUCTURES OF ARYLMOLYBDENUM(6+) NITRIDO COMPOUNDS - (2,4,6-ME(3)C(6)H(2))(3)MO-N AND (2-ME(2)NCH(2)C(6)H(4))(2)((T)BUO)MO-N
CAULTON, KG
CHISHOLM, MH
DOHERTY, S
FOLTING, K
ORGANOMETALLICS, 1995, 14 (05) : 2585 - 2588

← 1 2 3 4 5 →