First example of linear strings of equidistant gold atoms in crystals of [(2,4,6-Me3C6H2NC)(2)Au] [Au(GeCl3)(2)]

被引：23
|
作者：
Bauer, A [1 ]
Schneider, W [1 ]
Schmidbaur, H [1 ]
机构：
[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY
来源：
INORGANIC CHEMISTRY | 1997年 / 36卷 / 10期
关键词：
D O I：
10.1021/ic9701468
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Insertion of GeCl2 into the Au-Cl bond of (mesityl isocyanide)gold(I) chloride, followed by a ligand redistribution, leads to the title compound, which crystallizes in strings of alternating cations and anions with linear chains of equidistant gold atoms (Au1-Au2 = 3.435 Angstrom).
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页码：2225 / &
页数：3
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