First example of linear strings of equidistant gold atoms in crystals of [(2,4,6-Me3C6H2NC)(2)Au] [Au(GeCl3)(2)]

被引:23
|
作者
Bauer, A [1 ]
Schneider, W [1 ]
Schmidbaur, H [1 ]
机构
[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY
关键词
D O I
10.1021/ic9701468
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Insertion of GeCl2 into the Au-Cl bond of (mesityl isocyanide)gold(I) chloride, followed by a ligand redistribution, leads to the title compound, which crystallizes in strings of alternating cations and anions with linear chains of equidistant gold atoms (Au1-Au2 = 3.435 Angstrom).
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页码:2225 / &
页数:3
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