Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites

被引：120
|
作者：
Reetz, Manfred T. [1 ]
Li, Xiaoguang [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 20期
关键词：
D O I：
10.1039/b602320g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chiral diphosphonite, derived from BINOL and with an achiral diphenyl ether backbone, is an excellent ligand for the Ir-catalyzed asymmetric hydrogenation of quinolines; achiral P-ligands serving as possible additives (ee = 73-96%).
引用
收藏
页码：2159 / 2160
页数：2
相关论文
共 50 条
  • [41] Late-transition-metal complexes of BINOL-derived salens: Synthesis, structure, and reactivity
    DiMauro, EF
    Kozlowski, MC
    ORGANOMETALLICS, 2002, 21 (07) : 1454 - 1461
  • [42] First application of chiral phosphotriesters in asymmetric metal catalysis: enantioselective Zn-catalyzed hydrosilylation of ketones in the presence of BINOL-derived phosphates
    Ndimba, Alphonsine Ngo
    Roisnel, Thierry
    Argouarch, Gilles
    Lalli, Claudia
    COMPTES RENDUS CHIMIE, 2021, 24 (02) : 77 - 81
  • [43] Enantioselective Hydrogenation of the Double Bond of Exocyclic α,β-Unsaturated Carbonyl Compounds Catalyzed by Iridium/H8-BINOL-Derived Phosphine-Oxazoline Complexes
    Li, Qing
    Wan, Pin
    He, Yuwei
    Zhou, Yougui
    Li, Lanning
    Chen, Bin
    Duan, Kun
    Cao, Rihui
    Zhou, Zhongyuan
    Qiu, Liqin
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 3 (07) : 774 - 783
  • [44] ASYMMETRIC HYDROGENATION CATALYZED BY DIPHOSPHINITE RHODIUM COMPLEXES DERIVED FROM A SUGAR
    CULLEN, WR
    SUGI, Y
    TETRAHEDRON LETTERS, 1978, (19) : 1635 - 1636
  • [45] A modular design of ruthenium catalysts with diamine and BINOL-derived phosphinite ligands that are enantiomerically-matched for the effective asymmetric transfer hydrogenation of simple ketones
    Guo, RW
    Elpelt, C
    Chen, XH
    Song, DT
    Morris, RH
    CHEMICAL COMMUNICATIONS, 2005, (24) : 3050 - 3052
  • [46] Manganese-Catalyzed Asymmetric Hydrogenation of Quinolines Enabled by π-π Interaction
    Liu, Chenguang
    Wang, Mingyang
    Liu, Shihan
    Wang, Yujie
    Peng, Yong
    Lan, Yu
    Liu, Qiang
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (10) : 5108 - 5113
  • [47] Palladium(0)-catalyzed asymmetric C(sp3)-H arylation using a chiral binol-derived phosphate and an achiral ligand
    Yang, Lei
    Melot, Romain
    Neuburger, Markus
    Baudoin, Olivier
    CHEMICAL SCIENCE, 2017, 8 (02) : 1344 - 1349
  • [48] Visible light activated BINOL-derived chiroptical switches based on boron integrated hydrazone complexes
    van Vliet, Sven
    Alachouzos, Georgios
    de Vries, Folkert
    Pfeifer, Lukas
    Feringa, Ben L.
    CHEMICAL SCIENCE, 2022, 13 (33) : 9713 - 9718
  • [49] Progress in Iridium-Catalyzed Asymmetric Hydrogenation Reactions
    Zhang, Junfang
    Yang, Dingqiao
    Long, Yuhua
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2009, 29 (06) : 835 - 847
  • [50] Iridium-catalyzed asymmetric hydrogenation of vinyl ethers
    Zhu, Ye
    Burgess, Kevin
    ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (7-8) : 979 - 983
12345