Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites

被引：120
|
作者：
Reetz, Manfred T. [1 ]
Li, Xiaoguang [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 20期
关键词：
D O I：
10.1039/b602320g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chiral diphosphonite, derived from BINOL and with an achiral diphenyl ether backbone, is an excellent ligand for the Ir-catalyzed asymmetric hydrogenation of quinolines; achiral P-ligands serving as possible additives (ee = 73-96%).
引用
收藏
页码：2159 / 2160
页数：2
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