Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites

被引：120
|
作者：
Reetz, Manfred T. [1 ]
Li, Xiaoguang [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 20期
关键词：
D O I：
10.1039/b602320g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chiral diphosphonite, derived from BINOL and with an achiral diphenyl ether backbone, is an excellent ligand for the Ir-catalyzed asymmetric hydrogenation of quinolines; achiral P-ligands serving as possible additives (ee = 73-96%).
引用
收藏
页码：2159 / 2160
页数：2
相关论文
共 50 条
  • [31] Catalytic Asymmetric Reduction of α-Trifluoromethylated Imines with Catecholborane by BINOL-Derived Boro-phosphates
    He, Hualing
    Tang, Xiaoxue
    Cao, Yang
    Antilla, Jon C.
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (05): : 4336 - 4345
  • [32] Iridium-catalyzed asymmetric hydrogenation of quinazolinones
    Feng, Guang-Shou
    Zhao, Zi-Biao
    Shi, Lei
    Zhou, Yong-Gui
    ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (13) : 2250 - 2253
  • [33] Iridium-catalyzed asymmetric hydrogenation of olefins
    Roseblade, Stephen J.
    Pfaltz, Andreas
    ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (12) : 1402 - 1411
  • [34] Iridium-Catalyzed Asymmetric Hydrogenation of Imines
    Baeza, Alejandro
    Pfaltz, Andreas
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (13) : 4003 - 4009
  • [35] Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos
    Mrsic, Natasa
    Jerphagnon, Thomas
    Minnaard, Adriaan J.
    Feringa, Ben L.
    de Vries, Johannes G.
    ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (16) : 2549 - 2552
  • [36] Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands
    Willcox, Darren
    Carden, Jamie L.
    Ruddy, Adam J.
    Newman, Paul D.
    Melen, Rebecca L.
    DALTON TRANSACTIONS, 2020, 49 (08) : 2417 - 2420
  • [37] Highly Acidic BINOL-Derived Phosphoramidimidates and their Application in the BrOnsted Acid Catalyzed Synthesis of -Tocopherol
    Kaib, Philip S. J.
    List, Benjamin
    SYNLETT, 2016, 27 (01) : 156 - 158
  • [38] Highly enantioselective iridium-catalyzed hydrogenation of heteroaromatic compounds, quinolines
    Wang, WB
    Lu, SM
    Yang, PY
    Han, XW
    Zhou, YG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (35) : 10536 - 10537
  • [39] Heterogenised iridium complexes for the asymmetric hydrogenation of imines
    Margalef-Catalá, R
    Claver, C
    Salagre, P
    Fernández, E
    TETRAHEDRON-ASYMMETRY, 2000, 11 (07) : 1469 - 1476
  • [40] Catalysis of the Michael addition reaction by late transition metal complexes of BINOL-derived salens
    Annamalai, V
    DiMauro, EF
    Carroll, PJ
    Kozlowski, MC
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (05): : 1973 - 1981
12345