Cooperative Catalysis through Noncovalent Interactions

被引：70
|
作者：
Tang, Weijun [1 ]
Johnston, Steven [1 ]
Iggo, Jonathan A. [1 ]
Berry, Neil G. [1 ]
Phelan, Marie [2 ]
Lian, Luyun [2 ]
Bacsa, John [1 ]
Xiao, Jianliang [1 ]
机构：
[1] Univ Liverpool, Dept Chem, Liverpool Ctr Mat & Catalysis, Liverpool L69 7ZD, Merseyside, England
[2] Univ Liverpool, NMR Ctr Struct Biol, Inst Integrat Biol, Liverpool L69 7ZB, Merseyside, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 06期
基金：
英国工程与自然科学研究理事会;
关键词：
Bronsted acid; cooperative catalysis; hydrogenation; iridium; noncovalent interactions; TRANSITION-METAL; ASYMMETRIC HYDROGENATION; ENANTIOSELECTIVITY; ACTIVATION; COMPLEXES; MECHANISM; STRATEGY; IMINES; BONDS;
D O I：
10.1002/anie.201208774
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One of four: A chiral phosphoric acid enables asymmetric hydrogenation of imines with an achiral iridium catalyst by virtue of noncovalent interactions. These interactions lead to the formation of a highly organized ternary complex, and the hydride is transferred highly enantioselectively. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1668 / 1672
页数：5
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