Cooperative Catalysis through Noncovalent Interactions

被引：70

作者：

Tang, Weijun ^{[1
]}

Johnston, Steven ^{[1
]}

Iggo, Jonathan A. ^{[1
]}

Berry, Neil G. ^{[1
]}

Phelan, Marie ^{[2
]}

Lian, Luyun ^{[2
]}

Bacsa, John ^{[1
]}

Xiao, Jianliang ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool Ctr Mat & Catalysis, Liverpool L69 7ZD, Merseyside, England

[2] Univ Liverpool, NMR Ctr Struct Biol, Inst Integrat Biol, Liverpool L69 7ZB, Merseyside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 06期

基金：

英国工程与自然科学研究理事会;

关键词：

Bronsted acid; cooperative catalysis; hydrogenation; iridium; noncovalent interactions; TRANSITION-METAL; ASYMMETRIC HYDROGENATION; ENANTIOSELECTIVITY; ACTIVATION; COMPLEXES; MECHANISM; STRATEGY; IMINES; BONDS;

D O I：

10.1002/anie.201208774

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One of four: A chiral phosphoric acid enables asymmetric hydrogenation of imines with an achiral iridium catalyst by virtue of noncovalent interactions. These interactions lead to the formation of a highly organized ternary complex, and the hydride is transferred highly enantioselectively. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1668 / 1672

页数：5

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