Cooperative Catalysis through Noncovalent Interactions

被引：70
|
作者：
Tang, Weijun [1 ]
Johnston, Steven [1 ]
Iggo, Jonathan A. [1 ]
Berry, Neil G. [1 ]
Phelan, Marie [2 ]
Lian, Luyun [2 ]
Bacsa, John [1 ]
Xiao, Jianliang [1 ]
机构：
[1] Univ Liverpool, Dept Chem, Liverpool Ctr Mat & Catalysis, Liverpool L69 7ZD, Merseyside, England
[2] Univ Liverpool, NMR Ctr Struct Biol, Inst Integrat Biol, Liverpool L69 7ZB, Merseyside, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 06期
基金：
英国工程与自然科学研究理事会;
关键词：
Bronsted acid; cooperative catalysis; hydrogenation; iridium; noncovalent interactions; TRANSITION-METAL; ASYMMETRIC HYDROGENATION; ENANTIOSELECTIVITY; ACTIVATION; COMPLEXES; MECHANISM; STRATEGY; IMINES; BONDS;
D O I：
10.1002/anie.201208774
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One of four: A chiral phosphoric acid enables asymmetric hydrogenation of imines with an achiral iridium catalyst by virtue of noncovalent interactions. These interactions lead to the formation of a highly organized ternary complex, and the hydride is transferred highly enantioselectively. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1668 / 1672
页数：5
相关论文
共 50 条
  • [41] Pore-formation through Controlling Noncovalent Interactions in Polyelectrolyte Film
    Huang, Wei-pin
    Huang, Dan-ni
    Ren, Ke-feng
    Ji, Jian
    ACTA POLYMERICA SINICA, 2021, 52 (08): : 978 - 986
  • [42] Supramolecular polymers formed through hydrogen-bonded noncovalent interactions
    Wang Yujiang
    Tang Liming
    PROGRESS IN CHEMISTRY, 2006, 18 (2-3) : 308 - 316
  • [43] Reversibly Switching Bilayer Permeability and Release Modules of Photochromic Polymersomes Stabilized by Cooperative Noncovalent Interactions
    Wang, Xiaorui
    Hu, Jinming
    Liu, Guhuan
    Tian, Jie
    Wang, Huijuan
    Gong, Ming
    Liu, Shiyong
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (48) : 15262 - 15275
  • [44] Noncovalent Synthesis of Self-Assembled Nanotubes through Decoupled Hierarchical Cooperative Processes
    Vazquez-Gonzalez, Violeta
    Mayoral, Maria J.
    Chamorro, Raquel
    Hendrix, Marco M. R. M.
    Voets, Ilja K.
    Gonzalez-Rodriguez, David
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (41) : 16432 - 16438
  • [45] On the Role of Noncovalent Ligand-Substrate Interactions in Au(I) Catalysis: An Experimental and Computational Study of Protodeauration
    Jo, Taegeun
    Taschinski, Svenja
    Leach, Isaac F.
    Bauer, Christina
    Hashmi, A. Stephen K.
    Klein, Johannes E. M. N.
    ACS CATALYSIS, 2022, 12 (21) : 13158 - 13163
  • [46] Recent Developments in Enantioselective Transition Metal Catalysis Featuring Attractive Noncovalent Interactions between Ligand and Substrate
    Fanourakis, Alexander
    Docherty, Philip J.
    Chuentragool, Padon
    Phipps, Robert J.
    ACS CATALYSIS, 2020, 10 (18): : 10672 - 10714
  • [47] Heterobimetallic Lantern Complexes That Couple Antiferromagnetically through Noncovalent Pt•••Pt Interactions
    Baddour, Frederick G.
    Fiedler, Stephanie R.
    Shores, Matthew P.
    Golen, James A.
    Rheingold, Arnold L.
    Doerrer, Linda H.
    INORGANIC CHEMISTRY, 2013, 52 (09) : 4926 - 4933
  • [48] Material Adhesion through Direct Covalent Bond Formation Assisted by Noncovalent Interactions
    Osaki, Motofumi
    Sekine, Tomoko
    Yamaguchi, Hiroyasu
    Takashima, Yoshinori
    Harada, Akira
    ACS APPLIED POLYMER MATERIALS, 2021, 3 (04) : 2189 - 2196
  • [49] Cooperative Assembly of Pyrene-Functionalized Donor/Acceptor Blend for Ordered Nanomorphology by Intermolecular Noncovalent π-π Interactions
    Chen, Lie
    Peng, Siwan
    Chen, Yiwang
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (11) : 8115 - 8123
  • [50] Noncovalent Interactions of the Eggshell Membrane
    V. I. Ivanov-Omskii
    S. G. Yastrebov
    Technical Physics Letters, 2020, 46 : 896 - 897
12345