Polymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]

被引：3
|
作者：
Erturk, Erkan [1 ]
Tezeren, Mustafa Ali [2 ]
Tilki, Tahir [2 ]
Erdogan, Tuba [1 ]
Goren, Ahmet C. [3 ]
机构：
[1] TUBITAK Marmara Res Ctr, Inst Chem, TR-41470 Gebze, Kocaeli, Turkey
[2] Suleyman Demirel Univ, Dept Chem, TR-32260 Isparta, Turkey
[3] TUBITAK UME, Chem Grp Labs, TR-41470 Gebze, Kocaeli, Turkey
来源：
POLYMER INTERNATIONAL | 2012年 / 61卷 / 05期
关键词：
epoxide polymerization; iron; catalysis; RING-OPENING POLYMERIZATION; PHOTOINITIATED CATIONIC-POLYMERIZATION; CYCLOHEXENE OXIDE; ALUMINUM PORPHYRIN; IMMORTAL POLYMERIZATIONS; BETA-LACTONE; SALTS; INITIATORS; SYSTEM; ZINC;
D O I：
10.1002/pi.4141
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The readily available mixed-valent iron trifluoroacetate complex [Fe2IIIFeII(mu 3-O)(O2CCF3)6(H2O)3] is an effective catalyst for the polymerization of epoxides. A very small amount of the catalyst (1.00.01 mol%) could initiate the polymerization of cyclohexene oxide, cyclopentene oxide and epichlorohydrin. Based on quantitative end-group analysis by 19F NMR spectroscopy, a Lewis acid (LA?) catalyzed anionic reaction mechanism is proposed. Copyright (c) 2012 Society of Chemical Industry
引用
收藏
页码：795 / 799
页数：5
相关论文
共 50 条
  • [21] Structural transition at 225 K of the trinuclear Fe(III) heptanoate [Fe3O(O2CC6H13)6(H2O)3]NO3
    François, M
    Saleh, MI
    Rabu, P
    Souhassou, M
    Malaman, B
    Steinmetz, J
    SOLID STATE SCIENCES, 2005, 7 (10) : 1236 - 1246
  • [22] Zn2(O2CCF3)4 and Zn7O2(O2CCF3)10 - Syntheses and Crystal Structures
    van Gellecom, Nina
    Genchev, Georgi
    Frank, Walter
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2010, 66 : S247 - S247
  • [23] Magnetic relaxation in basic iron(III) carboxylate [Fe3O(O2CPh)6(H2O)3]ClO4•py
    Georgopoulou, Anastasia N.
    Sanakis, Yiannis
    Boudalis, Athanassios K.
    DALTON TRANSACTIONS, 2011, 40 (24) : 6371 - 6374
  • [24] Synthesis and crystal structure of KNa3[Fe3O(CH3COO)6(H2O)2]3 [α-P2W17Fe(H2O)O61]·32.5H2O
    N. V. Izarova
    M. N. Sokolov
    A. V. Virovets
    H. G. Platas
    V. P. Fedin
    Journal of Structural Chemistry, 2005, 46 : 147 - 153
  • [25] Synthesis and crystal structure of KNa3[Fe3O(CH3COO)6(H2O)2]3[α-P2W17Fe(H2O)O61]•32.5H2O
    Izarova, NV
    Sokolov, MN
    Virovets, AV
    Platas, HG
    Fedin, VP
    JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (01) : 147 - 153
  • [26] Mixed-valent vanadium substituted polyoxometalates: the wheel shaped [Rb3⊂{VVVIV3O7(H2O)6}2{H6P6W39O147(H2O)3}]15-
    Assran, Awatef S.
    Izarova, Natalya V.
    Kortz, Ulrich
    CRYSTENGCOMM, 2010, 12 (10): : 2684 - 2686
  • [27] The Crystal Structure of a Mixed-Metal Basic Trifluoroacetate of Aluminium and Zinc: [AlZn(μ4-O(O2CCF3)3]4
    Genchev, Georgi
    Frank, Walter
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2010, 66 : S244 - S244
  • [28] AN INVESTIGATION OF THE BONDING IN [RU2(O2CCF3)4] AND [RU2(O2CCF3)4(NO)2]
    CLARK, DL
    GREEN, JC
    REDFERN, CM
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (06): : 1037 - 1044
  • [29] DYNAMIC STRUCTURE OF MIXED-VALENT IRON COMPLEX OF [FE3O(COOCC13)6(CH3OH)3].1,5H2O WITH SPACE-TIME ELECTRON DELOCALIZATION
    SHILOV, GV
    PONOMAREV, VI
    ATOVMYAN, LO
    KOORDINATSIONNAYA KHIMIYA, 1990, 16 (02): : 230 - 237
  • [30] CRYSTAL, MOLECULAR, AND ELECTRONIC-STRUCTURE OF CARBOXYLATE [FE3O(CH3COO)6(H2O)3]NO3.4H2O
    TURTE, KI
    SHOVA, SG
    SPATAR, FA
    MAZUS, MD
    MALINOVSKII, TI
    JOURNAL OF STRUCTURAL CHEMISTRY, 1994, 35 (02) : 248 - 255
12345