Polymerization of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]

被引：3

作者：

Erturk, Erkan ^{[1
]}

Tezeren, Mustafa Ali ^{[2
]}

Tilki, Tahir ^{[2
]}

Erdogan, Tuba ^{[1
]}

Goren, Ahmet C. ^{[3
]}

机构：

[1] TUBITAK Marmara Res Ctr, Inst Chem, TR-41470 Gebze, Kocaeli, Turkey

[2] Suleyman Demirel Univ, Dept Chem, TR-32260 Isparta, Turkey

[3] TUBITAK UME, Chem Grp Labs, TR-41470 Gebze, Kocaeli, Turkey

来源：

POLYMER INTERNATIONAL | 2012年 / 61卷 / 05期

关键词：

epoxide polymerization; iron; catalysis; RING-OPENING POLYMERIZATION; PHOTOINITIATED CATIONIC-POLYMERIZATION; CYCLOHEXENE OXIDE; ALUMINUM PORPHYRIN; IMMORTAL POLYMERIZATIONS; BETA-LACTONE; SALTS; INITIATORS; SYSTEM; ZINC;

D O I：

10.1002/pi.4141

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The readily available mixed-valent iron trifluoroacetate complex [Fe2IIIFeII(mu 3-O)(O2CCF3)6(H2O)3] is an effective catalyst for the polymerization of epoxides. A very small amount of the catalyst (1.00.01 mol%) could initiate the polymerization of cyclohexene oxide, cyclopentene oxide and epichlorohydrin. Based on quantitative end-group analysis by 19F NMR spectroscopy, a Lewis acid (LA?) catalyzed anionic reaction mechanism is proposed. Copyright (c) 2012 Society of Chemical Industry

引用

页码：795 / 799

页数：5

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