Magnetic relaxation in basic iron(III) carboxylate [Fe3O(O2CPh)6(H2O)3]ClO4•py

被引：19
|
作者：
Georgopoulou, Anastasia N. [1 ]
Sanakis, Yiannis [1 ]
Boudalis, Athanassios K. [1 ]
机构：
[1] NCSR Demokritos, Inst Mat Sci, Aghia Paraskevi 15310, Greece
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 24期
关键词：
SPIN RELAXATION; COMPLEX; CLUSTERS;
D O I：
10.1039/c1dt10323g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The magnetic properties of the antiferromagnetic basic iron(III) carboxylate [Fe3O(O2CPh)(6)(H2O)(3)]ClO4 center dot py are studied by magnetic susceptometry and electron paramagnetic resonance spectrocopy. Ac susceptometry under moderate external magnetic fields reveals magnetic relaxation at liquid helium temperatures.
引用
收藏
页码：6371 / 6374
页数：4
相关论文
共 50 条
  • [1] Spin frustration and concealed asymmetry:: structure and magnetic spectrum of [Fe3O(O2CPh)6(py)3]ClO4•py
    Sowrey, FE
    Tilford, C
    Wocadlo, S
    Anson, CE
    Powell, AK
    Bennington, SM
    Montfrooij, W
    Jayasooriya, UA
    Cannon, RD
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (06): : 862 - 866
  • [2] Dynamic versus Static Character of the Magnetic Jahn-Teller Effect: Magnetostructural Studies of [Fe3O(O2CPh)6(py)3]ClO4•py
    Georgopoulou, Anastasia N.
    Margiolaki, Irene
    Psycharis, Vassilis
    Boudalis, Athanassios K.
    INORGANIC CHEMISTRY, 2017, 56 (02) : 762 - 772
  • [3] Mössbauer spectra of two extended series of basic iron(III) carboxylates [Fe3O(O2CR)6(H2O)6]A (A− = ClO4−, NO3−)
    Anastasia N. Georgopoulou
    Yiannis Sanakis
    Vassilis Psycharis
    Catherine P. Raptopoulou
    Athanassios K. Boudalis
    Hyperfine Interactions, 2010, 198 : 229 - 241
  • [4] The Crystal Structure of Indium Perchlorates [In(H2O)6](ClO4)3 and [In(H2O)6](ClO4)3 • 3H2O
    Ilyukhin, A. B.
    Malyarik, M. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (04) : 476 - 479
  • [5] Phase transitions of polycrystalline [Fe(H2O)6](ClO4)3 and [Cr(H2O)6](ClO4)3 studied by DSC
    E. Mikuli
    B. Grad
    K. Zaremba
    S. Wróbel
    Journal of Thermal Analysis and Calorimetry, 2004, 76 : 719 - 726
  • [6] Phase transitions of polycrystalline [Fe(H2O)6](ClO4)3 and [Cr(H2O)6](ClO4)3 studied by DSC
    Mikuli, E
    Grad, B
    Zaremba, K
    Wróbel, S
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2004, 76 (03) : 719 - 726
  • [7] Mossbauer spectra of two extended series of basic iron(III) carboxylates [Fe3O(O2CR)6(H2O)6]A (A- = ClO4-, NO3-)
    Georgopoulou, Anastasia N.
    Sanakis, Yiannis
    Psycharis, Vassilis
    Raptopoulou, Catherine P.
    Boudalis, Athanassios K.
    HYPERFINE INTERACTIONS, 2010, 198 (1-3): : 229 - 241
  • [8] [Fe3O（Ala）6（H2O）3]（ClO4）7和[Fe3O（Gly）6（H2O）3]（NO3）7·3H2O的顺磁共振谱及变温磁化率研究
    姚尚锋
    李健民
    光谱实验室, 2002, (02) : 153 - 156
  • [9] Synthesis, molecular structure and magnetic properties of [Fe6(μ3-O)2(OPri)2(μ-OPri)6(O2CPh)2(μ-O2CPh)4]
    Ammala, PS
    Batten, SR
    Cashion, JD
    Kepert, CM
    Moubaraki, B
    Murray, KS
    Spiccia, L
    West, BO
    INORGANICA CHIMICA ACTA, 2002, 331 (01) : 90 - 97
  • [10] Crystal structure and Raman spectra of [Fe(H2O)6]3+(ClO4−)3·3H2O
    L. S. Skogareva
    G. V. Shilov
    A. I. Karelin
    Journal of Structural Chemistry, 2012, 53 : 907 - 914
12345