Synchrotron-based highest resolution FTIR spectroscopy of chlorobenzene

被引：32

作者：

Albert, Sieghard ^{[1
,2
]}

Keppler, Karen ^{[1
]}

Lerch, Philippe ^{[2
]}

Quack, Martin ^{[1
]}

Wokaun, Alexander ^{[3
]}

机构：

[1] ETH, Phys Chem, CH-8093 Zurich, Switzerland

[2] Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland

[3] Paul Scherrer Inst, Energy Res Dept, CH-5232 Villigen, Switzerland

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2015年 / 315卷

基金：

欧洲研究理事会;

关键词：

Synchrotron; FTIR spectroscopy; High resolution spectroscopy; Infrared; Isotopes; Chlorobenzene; Pollutants; FAR-INFRARED-SPECTRUM; ROVIBRATIONAL ANALYSIS; ROTATIONAL SPECTRUM; VIBRATIONAL-MODES; PARITY VIOLATION; GLOBAL ANALYSIS; IR SPECTRUM; BANDS; TRANSITIONS; ISOTOPOMERS;

D O I：

10.1016/j.jms.2015.03.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

We report the Fourier Transform Infrared (FTIR) spectrum of chlorobenzene (C6H5Cl) measured using synchrotron radiation and the ETH-SLS 2009 prototype spectrometer at the Swiss Light Source (SLS). The maximum optical path difference of these measurements was 11.8 m leading to a resolution of better than 0.0008 cm(-1). The spectra were taken at room temperature in the range 600-900 cm(-1). It was possible to analyze the in-plane mode nu(12) of A(1) symmetry ((nu) over bar (0) = 706.6686 cm(-1)) and the out-of-plane mode nu(10b) of B-1 symmetry ((nu) over bar (0) = 741.2240 cm(-1)) of (C6H5Cl)-Cl-35. In addition, the ground state constant Delta(K) of (C6H5Cl)-Cl-35 has been readjusted using combination differences (CD). (C) 2015 Elsevier Inc. All rights reserved.

引用

页码：92 / 101

页数：10

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