Synchrotron-based highest resolution FTIR spectroscopy of chlorobenzene

被引：32
|
作者：
Albert, Sieghard [1 ,2 ]
Keppler, Karen [1 ]
Lerch, Philippe [2 ]
Quack, Martin [1 ]
Wokaun, Alexander [3 ]
机构：
[1] ETH, Phys Chem, CH-8093 Zurich, Switzerland
[2] Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland
[3] Paul Scherrer Inst, Energy Res Dept, CH-5232 Villigen, Switzerland
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 2015年 / 315卷
基金：
欧洲研究理事会;
关键词：
Synchrotron; FTIR spectroscopy; High resolution spectroscopy; Infrared; Isotopes; Chlorobenzene; Pollutants; FAR-INFRARED-SPECTRUM; ROVIBRATIONAL ANALYSIS; ROTATIONAL SPECTRUM; VIBRATIONAL-MODES; PARITY VIOLATION; GLOBAL ANALYSIS; IR SPECTRUM; BANDS; TRANSITIONS; ISOTOPOMERS;
D O I：
10.1016/j.jms.2015.03.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
We report the Fourier Transform Infrared (FTIR) spectrum of chlorobenzene (C6H5Cl) measured using synchrotron radiation and the ETH-SLS 2009 prototype spectrometer at the Swiss Light Source (SLS). The maximum optical path difference of these measurements was 11.8 m leading to a resolution of better than 0.0008 cm(-1). The spectra were taken at room temperature in the range 600-900 cm(-1). It was possible to analyze the in-plane mode nu(12) of A(1) symmetry ((nu) over bar (0) = 706.6686 cm(-1)) and the out-of-plane mode nu(10b) of B-1 symmetry ((nu) over bar (0) = 741.2240 cm(-1)) of (C6H5Cl)-Cl-35. In addition, the ground state constant Delta(K) of (C6H5Cl)-Cl-35 has been readjusted using combination differences (CD). (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码：92 / 101
页数：10
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