MONONUCLEAR COMPLEXES OF FIRST-ROW TRANSITION METALS WITH 2-MERCAPTOPYRIDINE N-OXIDE. CRYSTAL STRUCTURE OF TRIS (2-MERCAPTOPYRIDINE N-OXIDE) IRON (Ⅲ) DICHLOROMETHANE SOLVATE

被引：0

作者：

Hu Yong Han Chen Xue-Tai Dai Liang Weng Ling-Hong Kang Bei-ShengFujian Institute of Research on the Structure of Matter Mailer and Fashou Laboratory of Structural Chemistry. Chinese Academy of Sciences

机构：

来源：

结构化学 | 1993年 / 01期

关键词：

mode; IRON; MERCAPTOPYRIDINE N-OXIDE; MONONUCLEAR COMPLEXES OF FIRST-ROW TRANSITION METALS WITH 2-MERCAPTOPYRIDINE N-OXIDE; CRYSTAL STRUCTURE OF TRIS; DICHLOROMETHANE SOLVATE;

D O I：

10.14102/j.cnki.0254-5861.1993.01.010

中图分类号：

学科分类号：

摘要：

A range of transition metal complexes of 2-mercaptopyridine Noxide have been synthesized and studied by mass spcotroscopic technique. Crystal structure of Fe(ONC5H4S-o)3·CH2C12 has been determined. It crystallizes in mono clinic space group P 21. Crystal data; a=7. 638(3), b=15.038(3). c=9. 464(3) A.β-105.72 (3)°, V=1051. 8 A, Z = 2, Dc= 1. 64g/cm3 μ (MoKa) = 12. 8cm -, F(000) = 526. The structure was determined from 2080 reflections with f≥3σ(I) to convergence factor of R= 0. 051 (R, = 0. 052). The arrangement of the ligands gives the complex a meridional octahedral geometry with mean Fe -S, Fe-O distances and bite angles of 2.419A, 2. 009A , and 81.1°, respectively.

引用

页码：38 / 42

页数：5

共 50 条

[21] HETEROCYCLIC AND RELATED-COMPOUNDS DERIVED FROM DIPOTASSIUM 1,1-DIMERCAPTO-2,2-DICYANOETHYLENE AND SODIUM 2-MERCAPTOPYRIDINE N-OXIDE
DAMICO, JJ
RUMINSKI, PG
SUBA, LA
FREEMAN, JJ
DAHL, WE
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1985, 21 (03): : 307 - 314
[22] Synthesis and X-ray structure of the first lanthanide 2-mercaptopyridine N-oxide complex, tris-(1-hydroxy-2(1H)-pyridinethionato-O,S) bis[sulfinylbis(methane)]samarium(III)
Xiong, RG
Zuo, JL
You, XZ
Huang, XY
POLYHEDRON, 1996, 15 (19) : 3321 - 3324
[23] SYNTHESIS OF 2 TETRAPHENYLANTIMONY COMPLEXES OF PYRIDINE-N-OXIDES - CRYSTAL-STRUCTURE OF TETRAPHENYLANTIMONY (2-MERCAPTOPYRIDINE-N-OXIDE)
ARVANITIS, GM
BERARDINI, ME
ACTON, TB
DUMAS, PE
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 82 (1-4): : 127 - 135
[24] Oxidation of 2-mercaptopyridine N-oxide upon iodine agent: structural and FT-IR studies on charge-assisted hydrogen bonds CAHB(+) and I…I halogen interactions in 2,2′-dithiobis(pyridine N-oxide) ionic cocrystal
K. Wzgarda-Raj
A. J. Rybarczyk-Pirek
S. Wojtulewski
E. Pindelska
M. Palusiak
Structural Chemistry, 2019, 30 : 827 - 833
[25] Solvent extraction and separation of palladium from platinum group elements: Synthesis and characterization of 2-mercaptopyridine N-oxide-palladium (II) complex
Ngcephe, Ayanda M.
Sinha, Manish Kumar
Purcell, Walter
JOURNAL OF MOLECULAR STRUCTURE, 2020, 1199
[26] Synthesis, crystal structure and spectroscopic characterization of mono- and tetra-nuclear molybdenum(VI) complexes with 2-mercaptopyridine N-oxide: (n-Bu4N)2[MoO2(PT)2·Mo4O8(μ-O)2(μ3-O)2(PT)2]
Hong Liang
Zhen-Feng Chen
Rui-Xiang Hu
Qing Yu
Zhong-Yuan Zhou
Xiang-Ge Zhou
Transition Metal Chemistry, 2002, 27 : 102 - 104
[27] Synthesis, crystal structure and spectroscopic characterization of mono- and tetra-nuclear molybdenum(VI) complexes with 2-mercaptopyridine N-oxide:: (n-Bu4N)2[MoO2(PT)2•Mo4O8(μ-O)2(μ3-O)2(PT)2]
Liang, H
Chen, ZF
Hu, RX
Yu, Q
Zhou, ZY
Zhou, XG
TRANSITION METAL CHEMISTRY, 2002, 27 (01) : 102 - 104
[28] AMINE AND AMINE N-OXIDE COMPLEXES OF SOME FIRST-ROW TRANSITION-METAL TRIFLUOROACETATES AND TRICHLOROACETATES
AMASA, S
BROWN, DH
SHARP, DWA
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (19): : 2892 - &
[29] Oxidation of 2-mercaptopyridine N-oxide upon iodine agent: structural and FT-IR studies on charge-assisted hydrogen bonds CAHB(+) and I...I halogen interactions in 2,2-dithiobis(pyridine N-oxide) ionic cocrystal
Wzgarda-Raj, K.
Rybarczyk-Pirek, A. J.
Wojtulewski, S.
Pindelska, E.
Palusiak, M.
STRUCTURAL CHEMISTRY, 2019, 30 (03) : 827 - 833
[30] A tetranuclear cobalt complex with mercaptopyridine N-oxide as ligand. Synthesis and crystal structure of [Na3Co4(ae3-O)2(mpo)8(DMF)4]Br QQ 2DMF (mpo = 2-mercaptopyridine-N-oxide)
Jiang, F.
Hong, M.
Xie, X.
Cao, R.
International Journal of Modern Physics A, 1995, 101 (1-2):

← 1 2 3 4 5 →