SYNTHESIS OF 2 TETRAPHENYLANTIMONY COMPLEXES OF PYRIDINE-N-OXIDES - CRYSTAL-STRUCTURE OF TETRAPHENYLANTIMONY (2-MERCAPTOPYRIDINE-N-OXIDE)

被引：12
|
作者：
ARVANITIS, GM
BERARDINI, ME
ACTON, TB
DUMAS, PE
机构：
[1] Department of Chemistry, Trenton State College, Hillwood Lakes
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 82卷 / 1-4期
关键词：
ANTIMONY COMPLEXES; X-RAY; SELENIUM; SULFUR; ANTIMALARIAL ACTIVITY; BIOLOGICAL ACTIVITY; IR;
D O I：
10.1080/10426509308047416
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetraphenylantimony(2-mercaptopyridine-N-oxide) and tetraphenylantimony(2-selenopyridine-N-oxide) were synthesized from tetraphenylantimonybromide and the appropriate pyridine-N-oxide derivative. X-ray crystal structure analysis shows that the former compound crystallizes in space group C2/c, with a 29.095(2), b 10.6965(8), c 18.134(1), beta 94.154(5) and Z 8. The mercaptopyridine-N-oxide ligand binds via both its sulfur and oxygen atoms, leading to a distorted octahedral geometry about the antimony atom. Tetraphenylantimonypyridine-N-oxide derivatives of sulfur and selenium were found to possess antimalarial activity.
引用
收藏
页码：127 / 135
页数：9
相关论文
共 50 条
  • [1] Synthesis and structure of tetraphenylantimony N,N-diethyldithiocarbamate
    Sharutin, VV
    Sharutina, OK
    Platonova, TP
    Pakusina, AP
    Krivolapov, DB
    Gubaidullin, AT
    Litvinov, IA
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2002, 72 (09) : 1379 - 1382
  • [2] Synthesis and Structure of Tetraphenylantimony N,N-Diethyldithiocarbamate
    V. V. Sharutin
    O. K. Sharutina
    T. P. Platonova
    A. P. Pakusina
    D. B. Krivolapov
    A. T. Gubaidullin
    I. A. Litvinov
    Russian Journal of General Chemistry, 2002, 72 : 1379 - 1382
  • [3] CHELATES OF VANADIUM WITH 2-MERCAPTOPYRIDINE-N-OXIDE
    FRIESE, HJ
    UMLAND, F
    FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1977, 287 (4-5): : 298 - 303
  • [4] Tetraphenylantimony N-benzoylglycinate: synthesis and structure
    Sharutin, V. V.
    Sharutina, O. K.
    Khnykina, K. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 61 (02) : 180 - 182
  • [5] Tetraphenylantimony N-benzoylglycinate: synthesis and structure
    V. V. Sharutin
    O. K. Sharutina
    K. A. Khnykina
    Russian Journal of Inorganic Chemistry, 2016, 61 : 180 - 182
  • [6] 2-MERCAPTOPYRIDINE-N-OXIDE AND POSSIBILITIES OF ITS APPLICATION FOR CONCENTRATING
    BUSEV, AI
    BYRKO, VM
    NOVIKOVA, NN
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1972, (03): : 319 - &
  • [7] BIS(2-MERCAPTOPYRIDINE-N-OXIDE)OXOVANADIUM(IV) - SYNTHESIS, STRUCTURE AND ITS CONVERSION TO THE DICHLORO COMPLEX
    TSAGKALIDIS, W
    RODEWALD, D
    REHDER, D
    VERGOPOULOS, V
    INORGANICA CHIMICA ACTA, 1994, 219 (1-2) : 213 - 215
  • [8] A New Convenient Synthesis of Pyridine-N-oxides
    Tao LU
    Xin Zhong SHI
    Yi Ming WU(Dept.of Organic Chemistry
    ChineseChemicalLetters, 1996, (10) : 907 - 908
  • [9] A new convenient synthesis of pyridine-N-oxides
    Lu, T
    Shi, XZ
    Wu, YM
    CHINESE CHEMICAL LETTERS, 1996, 7 (10) : 907 - 908
  • [10] SYNTHESES AND ELECTROCHEMISTRY OF SOME TRANSITION-METAL COMPLEXES WITH 2-MERCAPTOPYRIDINE N-OXIDE AND CRYSTAL-STRUCTURE OF BIS(2-MERCAPTOPYRIDINE N-OXIDE)NICKEL(II)
    CHEN, XT
    HU, YH
    WU, DX
    WENG, LH
    KANG, BS
    POLYHEDRON, 1991, 10 (23-24) : 2651 - 2657
12345