SYNTHESIS OF 2 TETRAPHENYLANTIMONY COMPLEXES OF PYRIDINE-N-OXIDES - CRYSTAL-STRUCTURE OF TETRAPHENYLANTIMONY (2-MERCAPTOPYRIDINE-N-OXIDE)

被引：12
|
作者：
ARVANITIS, GM
BERARDINI, ME
ACTON, TB
DUMAS, PE
机构：
[1] Department of Chemistry, Trenton State College, Hillwood Lakes
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 82卷 / 1-4期
关键词：
ANTIMONY COMPLEXES; X-RAY; SELENIUM; SULFUR; ANTIMALARIAL ACTIVITY; BIOLOGICAL ACTIVITY; IR;
D O I：
10.1080/10426509308047416
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetraphenylantimony(2-mercaptopyridine-N-oxide) and tetraphenylantimony(2-selenopyridine-N-oxide) were synthesized from tetraphenylantimonybromide and the appropriate pyridine-N-oxide derivative. X-ray crystal structure analysis shows that the former compound crystallizes in space group C2/c, with a 29.095(2), b 10.6965(8), c 18.134(1), beta 94.154(5) and Z 8. The mercaptopyridine-N-oxide ligand binds via both its sulfur and oxygen atoms, leading to a distorted octahedral geometry about the antimony atom. Tetraphenylantimonypyridine-N-oxide derivatives of sulfur and selenium were found to possess antimalarial activity.
引用
收藏
页码：127 / 135
页数：9
相关论文
共 50 条
  • [31] RADIOLABELING OF EQUINE PLATELETS IN PLASMA WITH IN-III-(2-MERCAPTOPYRIDINE-N-OXIDE) AND THEIR INVIVO SURVIVAL
    COYNE, CP
    KELLY, AB
    HORNOF, WJ
    OBRIEN, TR
    PHILP, MS
    LAMB, JF
    AMERICAN JOURNAL OF VETERINARY RESEARCH, 1987, 48 (03) : 385 - 391
  • [32] Synthesis and crystal structure of [Sb(mpo)2Cl] (Hmpo=2-mercaptopyridine N-oxide)
    Niu, DZ
    Wang, JH
    Lu, ZS
    Chen, JT
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (11) : 1308 - 1311
  • [33] COMPLEXES OF TLBRCL2 WITH PYRIDINE N-OXIDE AND SOME SUBSTITUTED PYRIDINE N-OXIDES
    BERMEJO, MR
    FERNANDEZ, MI
    TAJES, J
    DEIBE, AG
    ANALES DE QUIMICA SERIE B-QUIMICA INORGANICA Y QUIMICA ANALYTICA, 1988, 84 (03): : 298 - 302
  • [34] Synthesis and crystal structure of Pr(mpo)3(DMSO)2 (Hmpo=2-mercaptopyridine N-oxide)
    Niu, DZ
    Mu, LL
    Lu, ZS
    Song, BL
    Sun, BW
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2004, 34 (03) : 195 - 198
  • [35] Synthesis and crystal structure of Pr(mpo)3(DMSO)2 (Hmpo = 2-mercaptopyridine N-oxide)
    De-Zhong Niu
    Lai-Long Mu
    Zai-Sheng Lu
    Bao-Ling Song
    Bai-Wang Sun
    Journal of Chemical Crystallography, 2004, 34 : 195 - 198
  • [36] MONONUCLEAR COMPLEXES OF FIRST-ROW TRANSITION METALS WITH 2-MERCAPTOPYRIDINE N-OXIDE. CRYSTAL STRUCTURE OF TRIS (2-MERCAPTOPYRIDINE N-OXIDE) IRON (Ⅲ) DICHLOROMETHANE SOLVATE
    Hu Yong Han Chen Xue-Tai Dai Liang Weng Ling-Hong Kang Bei-ShengFujian Institute of Research on the Structure of Matter Mailer and Fashou Laboratory of Structural Chemistry. Chinese Academy of Sciences
    结构化学, 1993, (01) : 38 - 42
  • [37] Thermodynamics of Zn2+ 2-mercaptopyridine-N-oxide and 2-hydroxypyridine-N-oxide interactions: Stability, solubility, activity coefficients and medium effects
    Bretti, Clemente
    Cigala, Rosalia Maria
    Crea, Francesco
    De Stefano, Concetta
    Lando, Gabriele
    Sammartano, Silvio
    JOURNAL OF MOLECULAR LIQUIDS, 2015, 211 : 876 - 884
  • [38] A tetranuclear cobalt complex with mercaptopyridine N-oxide as ligand. Synthesis and crystal structure of [Na3Co4(ae3-O)2(mpo)8(DMF)4]Br QQ 2DMF (mpo = 2-mercaptopyridine-N-oxide)
    Jiang, F.
    Hong, M.
    Xie, X.
    Cao, R.
    International Journal of Modern Physics A, 1995, 101 (1-2):
  • [39] 5-COORDINATE TRIPHENYLTIN(IV)-SULFUR COMPOUNDS - CRYSTAL-STRUCTURES OF THE AMINOETHANETHIOL AND 2-MERCAPTOPYRIDINE-N-OXIDE DERIVATIVES
    JAMES, BD
    MAGEE, RJ
    PATALINGHUG, WC
    SKELTON, BW
    WHITE, AH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 467 (01) : 51 - 55
  • [40] SYNTHESIS AND MOLECULAR-STRUCTURES OF COMPLEXES OF TLBRI2 WITH PYRIDINE N-OXIDE AND SOME SUBSTITUTED PYRIDINE N-OXIDES
    BERMEJO, MR
    SOLLEIRO, E
    RODRIGUEZ, A
    CASTINEIRAS, A
    POLYHEDRON, 1987, 6 (02) : 315 - 317
12345