MONONUCLEAR COMPLEXES OF FIRST-ROW TRANSITION METALS WITH 2-MERCAPTOPYRIDINE N-OXIDE. CRYSTAL STRUCTURE OF TRIS (2-MERCAPTOPYRIDINE N-OXIDE) IRON (Ⅲ) DICHLOROMETHANE SOLVATE

被引：0
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作者：
Hu Yong Han Chen Xue-Tai Dai Liang Weng Ling-Hong Kang Bei-ShengFujian Institute of Research on the Structure of Matter Mailer and Fashou Laboratory of Structural Chemistry. Chinese Academy of Sciences
机构：
来源：
结构化学 | 1993年 / 01期
关键词：
mode; IRON; MERCAPTOPYRIDINE N-OXIDE; MONONUCLEAR COMPLEXES OF FIRST-ROW TRANSITION METALS WITH 2-MERCAPTOPYRIDINE N-OXIDE; CRYSTAL STRUCTURE OF TRIS; DICHLOROMETHANE SOLVATE;
D O I：
10.14102/j.cnki.0254-5861.1993.01.010
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摘要：
A range of transition metal complexes of 2-mercaptopyridine Noxide have been synthesized and studied by mass spcotroscopic technique. Crystal structure of Fe(ONC5H4S-o)3·CH2C12 has been determined. It crystallizes in mono clinic space group P 21. Crystal data; a=7. 638(3), b=15.038(3). c=9. 464(3) A.β-105.72 (3)°, V=1051. 8 A, Z = 2, Dc= 1. 64g/cm3 μ (MoKa) = 12. 8cm -, F(000) = 526. The structure was determined from 2080 reflections with f≥3σ(I) to convergence factor of R= 0. 051 (R, = 0. 052). The arrangement of the ligands gives the complex a meridional octahedral geometry with mean Fe -S, Fe-O distances and bite angles of 2.419A, 2. 009A , and 81.1°, respectively.
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页码：38 / 42
页数：5
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